TY - JOUR
T1 - The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH3)2N C6H4-CH=CH-C5H4N-C 18H37 ]2M(dmit)2 (M=Cd, Ni)
AU - Zhai, Jin
AU - Huang, Chunhui
AU - Wei, Tian Xin
AU - Gan, Liangbing
AU - Cao, Hong
PY - 1999/3/26
Y1 - 1999/3/26
N2 - The photoelectric conversion and second harmonic generation properties of the complex bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium}bis(2-thione-1,3-dithiol-4,5-dimercapt)M,N[D2M(dmit) 2 where M=Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D2Cd(dmit)2 was evaluated to be 1.1% which is five-fold larger than that of bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium} iodide (DI) itself, while the second order nonlinear optical susceptibility χzzz2 was measured as 149.8 pm V-1 which is about the same as DI.
AB - The photoelectric conversion and second harmonic generation properties of the complex bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium}bis(2-thione-1,3-dithiol-4,5-dimercapt)M,N[D2M(dmit) 2 where M=Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D2Cd(dmit)2 was evaluated to be 1.1% which is five-fold larger than that of bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium} iodide (DI) itself, while the second order nonlinear optical susceptibility χzzz2 was measured as 149.8 pm V-1 which is about the same as DI.
KW - Hemicyanine cation
KW - Photoelectric conversion
KW - Second-harmonic generation
KW - Single-crystal structure
KW - Transition metal complex anions
UR - http://www.scopus.com/inward/record.url?scp=0000761243&partnerID=8YFLogxK
U2 - 10.1016/S0277-5387(99)00020-0
DO - 10.1016/S0277-5387(99)00020-0
M3 - Article
AN - SCOPUS:0000761243
SN - 0277-5387
VL - 18
SP - 1513
EP - 1518
JO - Polyhedron
JF - Polyhedron
IS - 10
ER -