The optical properties of ZnO sheets electrodeposited on ITO glass

Feifei Wang, Ruibin Liu, Anlian Pan, Li Cao, Ke Cheng, Bofei Xue, Geng Wang, Qingbo Meng, Jinghong Li, Qi Li, Yanguo Wang, Taihong Wang, Bingsuo Zou*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

68 Citations (Scopus)

Abstract

Large-scale hexagonal ZnO sheets were grown on ITO glass by cathodic electrodeposition in an aqueous zinc nitrate/potassium chloride solution at 60 °C and annealing at 350 °C for an hour. The sheets are about 3 μm in dimension and 100-300 nm in thickness. The ZnO sheets show many nano-pits on the surface and produce intense green luminescence at room temperature under femtosecond (fs) pulse ultraviolet (UV) light excitation. Both power-dependent photoluminescence spectra and time-resolved spectra were measured with varied excitation powers. Lasing phenomena occur at above 500 μJ/cm2 and the stimulated emission occurs with lifetime of less than 30 ps over 600 μJ/cm2. Additionally, the open-circuit photovoltage spectra indicate that the light-absorbing dye of RuL2(NCS)2 (N3) can be well adsorbed on the surface of ZnO sheets, which is useful for the dye-sensitized solar cells(DSSC).

Original languageEnglish
Pages (from-to)2000-2003
Number of pages4
JournalMaterials Letters
Volume61
Issue number10
DOIs
Publication statusPublished - Apr 2007
Externally publishedYes

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