The investigation of poly(methyl methacrylate-diallyl phthalate) gradient index materials by pyrolysis-capillary gas chromatography and pyrolysis-capillary gas chromatography / mass spectrometry

Aiqin Luo*, Bingheng Ge, Ruonong Fu, Jihua Ni, Jianqing Chen, Lin Deng, Qing He

*Corresponding author for this work

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Abstract

Poly(methyl methacrylate) (PMMA), poly(diallyl phthalate) (PDAP) and nine poly(MMA-DAP) standard samples whose compositions were known were investigated by means of pyrolysis capillary gas chromatography(Py-CGC) and their pyrolysis products were identified by pyrolysis capillary gas chromatography-mass spectrometry(Py-CGC/MS). The relationship between monomer feed ratio in copolymer and quantity of pyrolysates was drawn in a standard working curve. On these bases, the structure and composition of 14 cutting plates of a poly(MMA-DAP) GRIN material polymerized by a vapor transfer diffusion technique were analyzed by Py-CGC.

Original languageEnglish
Pages (from-to)327-334
Number of pages8
JournalJournal of Analytical and Applied Pyrolysis
Volume21
Issue number3
DOIs
Publication statusPublished - Nov 1991

Keywords

  • Gas chromatography
  • gradient-index (GRIN)
  • poly(MMA-DAP)
  • poly(diallyl phthalate) (PDAP)
  • poly(methyl methacrylate) (PMMA)
  • pyrolysis.

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Luo, A., Ge, B., Fu, R., Ni, J., Chen, J., Deng, L., & He, Q. (1991). The investigation of poly(methyl methacrylate-diallyl phthalate) gradient index materials by pyrolysis-capillary gas chromatography and pyrolysis-capillary gas chromatography / mass spectrometry. Journal of Analytical and Applied Pyrolysis, 21(3), 327-334. https://doi.org/10.1016/0165-2370(91)80007-U