The highly efficient 1,4-addition of TMSCN to aromatic enones catalyzed by CsF with water as the additive

Jingya Yang; Yinxian Wang; Shaoxiang Wu; Fu Xue Chen

doi:10.1055/s-0029-1218376

The highly efficient 1,4-addition of TMSCN to aromatic enones catalyzed by CsF with water as the additive

Jingya Yang, Yinxian Wang, Shaoxiang Wu, Fu Xue Chen^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

An efficient 1,4-addition of TMSCN to aromatic enones has been achieved in excellent yields (91-99%) by CsF (1 mol%) as the catalyst and H₂O (4 equiv) as the additive in refluxing dioxane within 2-7 hours.

Original language	English
Pages (from-to)	3365-3367
Number of pages	3
Journal	Synlett
Issue number	20
DOIs	https://doi.org/10.1055/s-0029-1218376
Publication status	Published - 2009

Keywords

1,4-addition reaction
CsF
Enones
Nitriles
Regioselectivity

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10.1055/s-0029-1218376

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title = "The highly efficient 1,4-addition of TMSCN to aromatic enones catalyzed by CsF with water as the additive",

abstract = "An efficient 1,4-addition of TMSCN to aromatic enones has been achieved in excellent yields (91-99%) by CsF (1 mol%) as the catalyst and H2O (4 equiv) as the additive in refluxing dioxane within 2-7 hours.",

keywords = "1,4-addition reaction, CsF, Enones, Nitriles, Regioselectivity",

author = "Jingya Yang and Yinxian Wang and Shaoxiang Wu and Chen, {Fu Xue}",

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AU - Yang, Jingya

AU - Wang, Yinxian

AU - Wu, Shaoxiang

AU - Chen, Fu Xue

PY - 2009

Y1 - 2009

N2 - An efficient 1,4-addition of TMSCN to aromatic enones has been achieved in excellent yields (91-99%) by CsF (1 mol%) as the catalyst and H2O (4 equiv) as the additive in refluxing dioxane within 2-7 hours.

AB - An efficient 1,4-addition of TMSCN to aromatic enones has been achieved in excellent yields (91-99%) by CsF (1 mol%) as the catalyst and H2O (4 equiv) as the additive in refluxing dioxane within 2-7 hours.

KW - 1,4-addition reaction

KW - CsF

KW - Enones

KW - Nitriles

KW - Regioselectivity

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U2 - 10.1055/s-0029-1218376

DO - 10.1055/s-0029-1218376

M3 - Article

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SP - 3365

EP - 3367

JO - Synlett

JF - Synlett

IS - 20

ER -

The highly efficient 1,4-addition of TMSCN to aromatic enones catalyzed by CsF with water as the additive

Abstract

Keywords

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