The evolution of the monoelectron dihydrogen bond H⋯e⋯H in the symmetric and asymmetric cluster anions (FH)n{e}(HF)m

Xi Yun Hao*, Zhi Ru Li, Di Wu, Ze Sheng Li, Chia Chung Sun

*Corresponding author for this work

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Abstract

The evolution of the monoelectron dihydrogen bond H···e···H in the symmetric and asymmetric cluster anions (FH)n{e} (HF)m was studied. This evolution shows a size effect of the subunits on the structure and the bond for the molecular cluster anions. The simplest bridge was formed by one excess electron and two positive charged hydrogen atoms.

Original languageEnglish
Pages (from-to)10939-10943
Number of pages5
JournalJournal of Chemical Physics
Volume118
Issue number24
DOIs
Publication statusPublished - 22 Jun 2003
Externally publishedYes

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Hao, X. Y., Li, Z. R., Wu, D., Li, Z. S., & Sun, C. C. (2003). The evolution of the monoelectron dihydrogen bond H⋯e⋯H in the symmetric and asymmetric cluster anions (FH)n{e}(HF)m. Journal of Chemical Physics, 118(24), 10939-10943. https://doi.org/10.1063/1.1574783