The effect of different substituent groups of auxiliary ligands on the photochromic behaviors of bipyridinium-based coordination polymers

Ping Ping Zhang; Xiao Dong Yang; Li Sun; Wen Bo Li; Jie Zhang

doi:10.1016/j.inoche.2016.11.008

The effect of different substituent groups of auxiliary ligands on the photochromic behaviors of bipyridinium-based coordination polymers

Ping Ping Zhang, Xiao Dong Yang, Li Sun, Wen Bo Li, Jie Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Two bipyridinium-based coordination polymers, {[Cd(BCbpy)₂(o-BDC)]·13H₂O} (1) and {[Cd(BCbpy)₂(SA)]·6H₂O} (2), have been synthesized and structurally characterized. Single-crystal X-ray diffraction analysis shows that the two compounds have similar one-dimensional coordination polymeric chain structures but different packing patterns. Compound 1 displays fast eye-detectable photochromic behavior while compound 2 is photoinert under 365 nm irradiation. The influence of different substituent groups in same site of auxiliary ligands on the photochromic behaviors of the two compounds has been studied in detail.

Original language	English
Pages (from-to)	8-11
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	75
DOIs	https://doi.org/10.1016/j.inoche.2016.11.008
Publication status	Published - 1 Jan 2017

Keywords

Bipyridinium
Coordination polymers
Photochromism

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10.1016/j.inoche.2016.11.008

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title = "The effect of different substituent groups of auxiliary ligands on the photochromic behaviors of bipyridinium-based coordination polymers",

abstract = "Two bipyridinium-based coordination polymers, {[Cd(BCbpy)2(o-BDC)]·13H2O} (1) and {[Cd(BCbpy)2(SA)]·6H2O} (2), have been synthesized and structurally characterized. Single-crystal X-ray diffraction analysis shows that the two compounds have similar one-dimensional coordination polymeric chain structures but different packing patterns. Compound 1 displays fast eye-detectable photochromic behavior while compound 2 is photoinert under 365 nm irradiation. The influence of different substituent groups in same site of auxiliary ligands on the photochromic behaviors of the two compounds has been studied in detail.",

keywords = "Bipyridinium, Coordination polymers, Photochromism",

author = "Zhang, {Ping Ping} and Yang, {Xiao Dong} and Li Sun and Li, {Wen Bo} and Jie Zhang",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

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doi = "10.1016/j.inoche.2016.11.008",

language = "English",

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T1 - The effect of different substituent groups of auxiliary ligands on the photochromic behaviors of bipyridinium-based coordination polymers

AU - Zhang, Ping Ping

AU - Yang, Xiao Dong

AU - Sun, Li

AU - Li, Wen Bo

AU - Zhang, Jie

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Two bipyridinium-based coordination polymers, {[Cd(BCbpy)2(o-BDC)]·13H2O} (1) and {[Cd(BCbpy)2(SA)]·6H2O} (2), have been synthesized and structurally characterized. Single-crystal X-ray diffraction analysis shows that the two compounds have similar one-dimensional coordination polymeric chain structures but different packing patterns. Compound 1 displays fast eye-detectable photochromic behavior while compound 2 is photoinert under 365 nm irradiation. The influence of different substituent groups in same site of auxiliary ligands on the photochromic behaviors of the two compounds has been studied in detail.

AB - Two bipyridinium-based coordination polymers, {[Cd(BCbpy)2(o-BDC)]·13H2O} (1) and {[Cd(BCbpy)2(SA)]·6H2O} (2), have been synthesized and structurally characterized. Single-crystal X-ray diffraction analysis shows that the two compounds have similar one-dimensional coordination polymeric chain structures but different packing patterns. Compound 1 displays fast eye-detectable photochromic behavior while compound 2 is photoinert under 365 nm irradiation. The influence of different substituent groups in same site of auxiliary ligands on the photochromic behaviors of the two compounds has been studied in detail.

KW - Bipyridinium

KW - Coordination polymers

KW - Photochromism

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DO - 10.1016/j.inoche.2016.11.008

M3 - Article

AN - SCOPUS:84999749667

SN - 1387-7003

VL - 75

SP - 8

EP - 11

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

The effect of different substituent groups of auxiliary ligands on the photochromic behaviors of bipyridinium-based coordination polymers

Abstract

Keywords

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