The construction of two novel interpenetrating diamondoid networks presenting unusual [3 + 2] and [4 + 4] modes

Xian Min Guo, Yong Nian Yan, Hua Dong Guo*, Nan Wang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Two novel coordination polymers, [Co(1,4-ndc)(bipe)] (1), [Cd2(bdc)2(bipe)2]·2H2O (2) (bipe=bis(4-imidazolphenoxy)ethane, H2bdc=1,4-benzenedicarboxylic acid and 1,4-H2ndc=naphthalene-1,4-dicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features a five-fold interpenetration of dia network in a [3+2] mode. Compound 2 shows an eight-fold interpenetration of dia network in a [4+4] mode. In addition, compound 2 shows an emission at 435nm when it was excitated at 332nm.

Original languageEnglish
Article number6100
Pages (from-to)105-108
Number of pages4
JournalInorganic Chemistry Communications
Volume61
DOIs
Publication statusPublished - 1 Nov 2015
Externally publishedYes

Keywords

  • Coordination polymers
  • Diamondoid network
  • Entanglement
  • [3 + 2] mode
  • [4 + 4] mode

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