Abstract
Two novel coordination polymers, [Co(1,4-ndc)(bipe)] (1), [Cd2(bdc)2(bipe)2]·2H2O (2) (bipe=bis(4-imidazolphenoxy)ethane, H2bdc=1,4-benzenedicarboxylic acid and 1,4-H2ndc=naphthalene-1,4-dicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features a five-fold interpenetration of dia network in a [3+2] mode. Compound 2 shows an eight-fold interpenetration of dia network in a [4+4] mode. In addition, compound 2 shows an emission at 435nm when it was excitated at 332nm.
Original language | English |
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Article number | 6100 |
Pages (from-to) | 105-108 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 61 |
DOIs | |
Publication status | Published - 1 Nov 2015 |
Externally published | Yes |
Keywords
- Coordination polymers
- Diamondoid network
- Entanglement
- [3 + 2] mode
- [4 + 4] mode
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Guo, X. M., Yan, Y. N., Guo, H. D., & Wang, N. (2015). The construction of two novel interpenetrating diamondoid networks presenting unusual [3 + 2] and [4 + 4] modes. Inorganic Chemistry Communications, 61, 105-108. Article 6100. https://doi.org/10.1016/j.inoche.2015.09.003