Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

Zhongqiang Zhang; Di Di; Jingshuo Zhai; Lili Wu; Qinlei Zhu; Yanqing Xu; Rudan Huang

doi:10.1007/s40242-014-3434-2

Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

Zhongqiang Zhang, Di Di, Jingshuo Zhai, Lili Wu, Qinlei Zhu, Yanqing Xu, Rudan Huang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Two complexes, Co(Hbim)₂(NCS)₂(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]_n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

Original language	English
Pages (from-to)	185-189
Number of pages	5
Journal	Chemical Research in Chinese Universities
Volume	30
Issue number	2
DOIs	https://doi.org/10.1007/s40242-014-3434-2
Publication status	Published - Apr 2014

Keywords

Chemical synthesis
Crystal structure
Luminescence property
Magnetic property

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10.1007/s40242-014-3434-2

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title = "Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand",

abstract = "Two complexes, Co(Hbim)2(NCS)2(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.",

keywords = "Chemical synthesis, Crystal structure, Luminescence property, Magnetic property",

author = "Zhongqiang Zhang and Di Di and Jingshuo Zhai and Lili Wu and Qinlei Zhu and Yanqing Xu and Rudan Huang",

year = "2014",

month = apr,

doi = "10.1007/s40242-014-3434-2",

language = "English",

volume = "30",

pages = "185--189",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

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TY - JOUR

T1 - Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

AU - Zhang, Zhongqiang

AU - Di, Di

AU - Zhai, Jingshuo

AU - Wu, Lili

AU - Zhu, Qinlei

AU - Xu, Yanqing

AU - Huang, Rudan

PY - 2014/4

Y1 - 2014/4

N2 - Two complexes, Co(Hbim)2(NCS)2(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

AB - Two complexes, Co(Hbim)2(NCS)2(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

KW - Chemical synthesis

KW - Crystal structure

KW - Luminescence property

KW - Magnetic property

UR - http://www.scopus.com/inward/record.url?scp=84897947563&partnerID=8YFLogxK

U2 - 10.1007/s40242-014-3434-2

DO - 10.1007/s40242-014-3434-2

M3 - Article

AN - SCOPUS:84897947563

SN - 1005-9040

VL - 30

SP - 185

EP - 189

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 2

ER -

Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

Abstract

Keywords

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