Synthesis, structure and magnetic property of a new neodymium-adipate coordination polymer with large guest molecules

L. M. Duan; L. Ye; Y. B. Liu; F. T. Xie; J. H. Yu; J. Q. Xu

Synthesis, structure and magnetic property of a new neodymium-adipate coordination polymer with large guest molecules

L. M. Duan, L. Ye, Y. B. Liu, F. T. Xie, J. H. Yu, J. Q. Xu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A new lanthanide-adipate coordination polymer, {[Nd₂(ad) ₃(H₂O)₄](H₂ad)·4H ₂O}_n (1) (H₂ad = adipic acid), has been hydrothermally synthesized and structurally characterized by X-ray single crystal structure analysis, elemental analysis, infrared spectrum, thermogravimetric analysis and temperature-dependent magnetic susceptibility. The three-dimensional structure of compound 1 is based on edge-sharing NdO ₈(H₂O)₂ polyhedron chains, which were interconnected by twisted or extended carbon chains of the adipate ligands in [010] and [001] directions, respectively. The network contains large channels with adipic acid and lattice water acting as guest molecules. Above 50 K, the magnetic susceptibility data of 1 can be fitted to the Curie-Weiss law with θ = - 41.0 K and c = 3.52 emu Kmol^-1.

Original language	English
Pages (from-to)	1835-1842
Number of pages	8
Journal	Polish Journal of Chemistry
Volume	79
Issue number	12
Publication status	Published - Dec 2005
Externally published	Yes

Keywords

Adipic acid
Guest molecules
Hydrothermal synthesis
Neodymium compound

Cite this

@article{c1a8bec04f5f49358ff3d6e48c0f522e,

title = "Synthesis, structure and magnetic property of a new neodymium-adipate coordination polymer with large guest molecules",

abstract = "A new lanthanide-adipate coordination polymer, {[Nd2(ad) 3(H2O)4](H2ad)·4H 2O}n (1) (H2ad = adipic acid), has been hydrothermally synthesized and structurally characterized by X-ray single crystal structure analysis, elemental analysis, infrared spectrum, thermogravimetric analysis and temperature-dependent magnetic susceptibility. The three-dimensional structure of compound 1 is based on edge-sharing NdO 8(H2O)2 polyhedron chains, which were interconnected by twisted or extended carbon chains of the adipate ligands in [010] and [001] directions, respectively. The network contains large channels with adipic acid and lattice water acting as guest molecules. Above 50 K, the magnetic susceptibility data of 1 can be fitted to the Curie-Weiss law with θ = - 41.0 K and c = 3.52 emu Kmol-1.",

keywords = "Adipic acid, Guest molecules, Hydrothermal synthesis, Neodymium compound",

author = "Duan, {L. M.} and L. Ye and Liu, {Y. B.} and Xie, {F. T.} and Yu, {J. H.} and Xu, {J. Q.}",

year = "2005",

month = dec,

language = "English",

volume = "79",

pages = "1835--1842",

journal = "Polish Journal of Chemistry",

issn = "0137-5083",

publisher = "Polish Chemical Society",

number = "12",

}

TY - JOUR

T1 - Synthesis, structure and magnetic property of a new neodymium-adipate coordination polymer with large guest molecules

AU - Duan, L. M.

AU - Ye, L.

AU - Liu, Y. B.

AU - Xie, F. T.

AU - Yu, J. H.

AU - Xu, J. Q.

PY - 2005/12

Y1 - 2005/12

N2 - A new lanthanide-adipate coordination polymer, {[Nd2(ad) 3(H2O)4](H2ad)·4H 2O}n (1) (H2ad = adipic acid), has been hydrothermally synthesized and structurally characterized by X-ray single crystal structure analysis, elemental analysis, infrared spectrum, thermogravimetric analysis and temperature-dependent magnetic susceptibility. The three-dimensional structure of compound 1 is based on edge-sharing NdO 8(H2O)2 polyhedron chains, which were interconnected by twisted or extended carbon chains of the adipate ligands in [010] and [001] directions, respectively. The network contains large channels with adipic acid and lattice water acting as guest molecules. Above 50 K, the magnetic susceptibility data of 1 can be fitted to the Curie-Weiss law with θ = - 41.0 K and c = 3.52 emu Kmol-1.

AB - A new lanthanide-adipate coordination polymer, {[Nd2(ad) 3(H2O)4](H2ad)·4H 2O}n (1) (H2ad = adipic acid), has been hydrothermally synthesized and structurally characterized by X-ray single crystal structure analysis, elemental analysis, infrared spectrum, thermogravimetric analysis and temperature-dependent magnetic susceptibility. The three-dimensional structure of compound 1 is based on edge-sharing NdO 8(H2O)2 polyhedron chains, which were interconnected by twisted or extended carbon chains of the adipate ligands in [010] and [001] directions, respectively. The network contains large channels with adipic acid and lattice water acting as guest molecules. Above 50 K, the magnetic susceptibility data of 1 can be fitted to the Curie-Weiss law with θ = - 41.0 K and c = 3.52 emu Kmol-1.

KW - Adipic acid

KW - Guest molecules

KW - Hydrothermal synthesis

KW - Neodymium compound

UR - http://www.scopus.com/inward/record.url?scp=31544443257&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:31544443257

SN - 0137-5083

VL - 79

SP - 1835

EP - 1842

JO - Polish Journal of Chemistry

JF - Polish Journal of Chemistry

IS - 12

ER -

Synthesis, structure and magnetic property of a new neodymium-adipate coordination polymer with large guest molecules

Abstract

Keywords

Other files and links

Fingerprint

Cite this