Synthesis of Stable Shape-Controlled Catalytically Active β-Palladium Hydride

Zipeng Zhao; Xiaoqing Huang; Mufan Li; Gongming Wang; Chain Lee; Enbo Zhu; Xiangfeng Duan; Yu Huang

doi:10.1021/jacs.5b11543

Synthesis of Stable Shape-Controlled Catalytically Active β-Palladium Hydride

Zipeng Zhao, Xiaoqing Huang, Mufan Li, Gongming Wang, Chain Lee, Enbo Zhu, Xiangfeng Duan, Yu Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

128 Citations (Scopus)

Abstract

We have developed an efficient strategy for the production of stable β-palladium hydride (PdH_0.43) nanocrystals with controllable shapes and remarkable stability. The as-synthesized PdH_0.43 nanocrystals showed impressive stability in air at room temperature for over 10 months, which has enabled the investigation of their catalytic property for the first time. The prepared PdH_0.43 nanocrystals served as highly efficient catalysts in the oxidation of methanol, showing higher activity than their Pd counterparts. These studies opened a door for further exploration of β-palladium hydride-based nanomaterials as a new class of promising catalytic materials and beyond.

Original language	English
Pages (from-to)	15672-15675
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	50
DOIs	https://doi.org/10.1021/jacs.5b11543
Publication status	Published - 23 Dec 2015
Externally published	Yes

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title = "Synthesis of Stable Shape-Controlled Catalytically Active β-Palladium Hydride",

abstract = "We have developed an efficient strategy for the production of stable β-palladium hydride (PdH0.43) nanocrystals with controllable shapes and remarkable stability. The as-synthesized PdH0.43 nanocrystals showed impressive stability in air at room temperature for over 10 months, which has enabled the investigation of their catalytic property for the first time. The prepared PdH0.43 nanocrystals served as highly efficient catalysts in the oxidation of methanol, showing higher activity than their Pd counterparts. These studies opened a door for further exploration of β-palladium hydride-based nanomaterials as a new class of promising catalytic materials and beyond.",

author = "Zipeng Zhao and Xiaoqing Huang and Mufan Li and Gongming Wang and Chain Lee and Enbo Zhu and Xiangfeng Duan and Yu Huang",

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AU - Zhao, Zipeng

AU - Huang, Xiaoqing

AU - Li, Mufan

AU - Wang, Gongming

AU - Lee, Chain

AU - Zhu, Enbo

AU - Duan, Xiangfeng

AU - Huang, Yu

PY - 2015/12/23

Y1 - 2015/12/23

N2 - We have developed an efficient strategy for the production of stable β-palladium hydride (PdH0.43) nanocrystals with controllable shapes and remarkable stability. The as-synthesized PdH0.43 nanocrystals showed impressive stability in air at room temperature for over 10 months, which has enabled the investigation of their catalytic property for the first time. The prepared PdH0.43 nanocrystals served as highly efficient catalysts in the oxidation of methanol, showing higher activity than their Pd counterparts. These studies opened a door for further exploration of β-palladium hydride-based nanomaterials as a new class of promising catalytic materials and beyond.

AB - We have developed an efficient strategy for the production of stable β-palladium hydride (PdH0.43) nanocrystals with controllable shapes and remarkable stability. The as-synthesized PdH0.43 nanocrystals showed impressive stability in air at room temperature for over 10 months, which has enabled the investigation of their catalytic property for the first time. The prepared PdH0.43 nanocrystals served as highly efficient catalysts in the oxidation of methanol, showing higher activity than their Pd counterparts. These studies opened a door for further exploration of β-palladium hydride-based nanomaterials as a new class of promising catalytic materials and beyond.

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M3 - Article

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VL - 137

SP - 15672

EP - 15675

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 50

ER -

Synthesis of Stable Shape-Controlled Catalytically Active β-Palladium Hydride

Abstract

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