Zhou, M., Liu, J., Ling, C., Ge, Y., Chen, B., Tan, C., Fan, Z., Huang, J., Chen, J., Liu, Z., Huang, Z., Ge, J., Cheng, H., Chen, Y., Dai, L., Yin, P., Zhang, X., Yun, Q., Wang, J., & Zhang, H. (2022). Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation. Advanced Materials, 34(1), Article 2106115. https://doi.org/10.1002/adma.202106115
Zhou, Ming ; Liu, Jiawei ; Ling, Chongyi et al. / Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation. In: Advanced Materials. 2022 ; Vol. 34, No. 1.
@article{8ef91c2f994d4faa9ea3e4c6cb187965,
title = "Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation",
abstract = "The crystal phase of nanomaterials is one of the key parameters determining their physicochemical properties and performance in various applications. However, it still remains a great challenge to synthesize nanomaterials with different crystal phases while maintaining the same composition, size, and morphology. Here, a facile, one-pot, wet-chemical method is reported to synthesize Pd3Sn nanorods with comparable size and morphology but different crystal phases, that is, an ordered intermetallic and a disordered alloy with L12 and face-centered cubic (fcc) phases, respectively. The crystal phase of the as-synthesized Pd3Sn nanorods is easily tuned by altering the types of tin precursors and solvents. Moreover, the approach can also be used to synthesize ternary PdCuSn nanorods with the L12 crystal phase. When used as electrocatalysts, the L12 Pd3Sn nanorods exhibit superior electrocatalytic performance toward the ethanol oxidation reaction (EOR) compared to their fcc counterpart. Impressively, compared to the L12 Pd3Sn nanorods, the ternary L12 PdCuSn nanorods exhibit more enhanced electrocatalytic performance toward the EOR, yielding a high mass current density up to 6.22 A mgPd−1, which is superior to the commercial Pd/C catalyst and among the best reported Pd-based EOR electrocatalysts.",
author = "Ming Zhou and Jiawei Liu and Chongyi Ling and Yiyao Ge and Bo Chen and Chaoliang Tan and Zhanxi Fan and Jingtao Huang and Junze Chen and Zhengqing Liu and Zhiqi Huang and Jingjie Ge and Hongfei Cheng and Ye Chen and Lei Dai and Pengfei Yin and Xiao Zhang and Qinbai Yun and Jinlan Wang and Hua Zhang",
note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",
year = "2022",
month = jan,
day = "6",
doi = "10.1002/adma.202106115",
language = "English",
volume = "34",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-Blackwell",
number = "1",
}
Zhou, M, Liu, J, Ling, C, Ge, Y, Chen, B, Tan, C, Fan, Z, Huang, J, Chen, J, Liu, Z, Huang, Z, Ge, J, Cheng, H, Chen, Y, Dai, L, Yin, P, Zhang, X, Yun, Q, Wang, J & Zhang, H 2022, 'Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation', Advanced Materials, vol. 34, no. 1, 2106115. https://doi.org/10.1002/adma.202106115
Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation. / Zhou, Ming; Liu, Jiawei; Ling, Chongyi et al.
In:
Advanced Materials, Vol. 34, No. 1, 2106115, 06.01.2022.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation
AU - Zhou, Ming
AU - Liu, Jiawei
AU - Ling, Chongyi
AU - Ge, Yiyao
AU - Chen, Bo
AU - Tan, Chaoliang
AU - Fan, Zhanxi
AU - Huang, Jingtao
AU - Chen, Junze
AU - Liu, Zhengqing
AU - Huang, Zhiqi
AU - Ge, Jingjie
AU - Cheng, Hongfei
AU - Chen, Ye
AU - Dai, Lei
AU - Yin, Pengfei
AU - Zhang, Xiao
AU - Yun, Qinbai
AU - Wang, Jinlan
AU - Zhang, Hua
N1 - Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2022/1/6
Y1 - 2022/1/6
N2 - The crystal phase of nanomaterials is one of the key parameters determining their physicochemical properties and performance in various applications. However, it still remains a great challenge to synthesize nanomaterials with different crystal phases while maintaining the same composition, size, and morphology. Here, a facile, one-pot, wet-chemical method is reported to synthesize Pd3Sn nanorods with comparable size and morphology but different crystal phases, that is, an ordered intermetallic and a disordered alloy with L12 and face-centered cubic (fcc) phases, respectively. The crystal phase of the as-synthesized Pd3Sn nanorods is easily tuned by altering the types of tin precursors and solvents. Moreover, the approach can also be used to synthesize ternary PdCuSn nanorods with the L12 crystal phase. When used as electrocatalysts, the L12 Pd3Sn nanorods exhibit superior electrocatalytic performance toward the ethanol oxidation reaction (EOR) compared to their fcc counterpart. Impressively, compared to the L12 Pd3Sn nanorods, the ternary L12 PdCuSn nanorods exhibit more enhanced electrocatalytic performance toward the EOR, yielding a high mass current density up to 6.22 A mgPd−1, which is superior to the commercial Pd/C catalyst and among the best reported Pd-based EOR electrocatalysts.
AB - The crystal phase of nanomaterials is one of the key parameters determining their physicochemical properties and performance in various applications. However, it still remains a great challenge to synthesize nanomaterials with different crystal phases while maintaining the same composition, size, and morphology. Here, a facile, one-pot, wet-chemical method is reported to synthesize Pd3Sn nanorods with comparable size and morphology but different crystal phases, that is, an ordered intermetallic and a disordered alloy with L12 and face-centered cubic (fcc) phases, respectively. The crystal phase of the as-synthesized Pd3Sn nanorods is easily tuned by altering the types of tin precursors and solvents. Moreover, the approach can also be used to synthesize ternary PdCuSn nanorods with the L12 crystal phase. When used as electrocatalysts, the L12 Pd3Sn nanorods exhibit superior electrocatalytic performance toward the ethanol oxidation reaction (EOR) compared to their fcc counterpart. Impressively, compared to the L12 Pd3Sn nanorods, the ternary L12 PdCuSn nanorods exhibit more enhanced electrocatalytic performance toward the EOR, yielding a high mass current density up to 6.22 A mgPd−1, which is superior to the commercial Pd/C catalyst and among the best reported Pd-based EOR electrocatalysts.
UR - http://www.scopus.com/inward/record.url?scp=85117716863&partnerID=8YFLogxK
U2 - 10.1002/adma.202106115
DO - 10.1002/adma.202106115
M3 - Article
C2 - 34601769
AN - SCOPUS:85117716863
SN - 0935-9648
VL - 34
JO - Advanced Materials
JF - Advanced Materials
IS - 1
M1 - 2106115
ER -
Zhou M, Liu J, Ling C, Ge Y, Chen B, Tan C et al. Synthesis of Pd3Sn and PdCuSn Nanorods with L12 Phase for Highly Efficient Electrocatalytic Ethanol Oxidation. Advanced Materials. 2022 Jan 6;34(1):2106115. doi: 10.1002/adma.202106115