Synthesis of Nitroarenes under Microwave

Xiaohui Yan; Jiarong Li; Qi Zhang; Daxin Shi

doi:10.6023/cjoc201610030

Synthesis of Nitroarenes under Microwave

Xiaohui Yan, Jiarong Li, Qi Zhang, Daxin Shi^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The reaction of arylboronic acids with bismuth(III) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120℃) for 1 min in 1,2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.

Original language	English
Pages (from-to)	1450-1455
Number of pages	6
Journal	Chinese Journal of Organic Chemistry
Volume	37
Issue number	6
DOIs	https://doi.org/10.6023/cjoc201610030
Publication status	Published - 1 Jun 2017

Keywords

Arylboronic acids
Bismuth(III) nitrate pentahydrate
Free radical conversion
Microwave
Nitroarenes

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10.6023/cjoc201610030

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title = "Synthesis of Nitroarenes under Microwave",

abstract = "The reaction of arylboronic acids with bismuth(III) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120℃) for 1 min in 1,2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.",

keywords = "Arylboronic acids, Bismuth(III) nitrate pentahydrate, Free radical conversion, Microwave, Nitroarenes",

author = "Xiaohui Yan and Jiarong Li and Qi Zhang and Daxin Shi",

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year = "2017",

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T1 - Synthesis of Nitroarenes under Microwave

AU - Yan, Xiaohui

AU - Li, Jiarong

AU - Zhang, Qi

AU - Shi, Daxin

PY - 2017/6/1

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N2 - The reaction of arylboronic acids with bismuth(III) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120℃) for 1 min in 1,2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.

AB - The reaction of arylboronic acids with bismuth(III) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120℃) for 1 min in 1,2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.

KW - Arylboronic acids

KW - Bismuth(III) nitrate pentahydrate

KW - Free radical conversion

KW - Microwave

KW - Nitroarenes

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DO - 10.6023/cjoc201610030

M3 - Article

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SP - 1450

EP - 1455

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 6

ER -

Synthesis of Nitroarenes under Microwave

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Keywords

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