Synthesis of metallophthalocyanine covalent organic frameworks that exhibit high carrier mobility and photoconductivity

Xuesong Ding*, Jia Guo, Xiao Feng, Yoshihito Honsho, Jingdong Guo, Shu Seki, Phornphimon Maitarad, Akinori Saeki, Shigeru Nagase, Donglin Jiang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

462 Citations (Scopus)

Abstract

A light COF: Two-dimensional covalent organic frameworks of a nickel phthalocyanine have been synthesized. Owing to well-ordered stacking of the phthalocyanine units, the resulting 2D framework provides enhanced and broad light absorbance and facilitates charge transport. The material becomes highly photoconductive and is exceptionally sensitive to deep-red visible and near-infrared light.

Original languageEnglish
Pages (from-to)1289-1293
Number of pages5
JournalAngewandte Chemie - International Edition
Volume50
Issue number6
DOIs
Publication statusPublished - 7 Feb 2011
Externally publishedYes

Keywords

  • carrier transport
  • covalent organic frameworks
  • photoconduction
  • phthalocyanines
  • porous materials

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