Synthesis of hexaallylhexaazaisowurtzitane

Xin Le Li; Cheng Hui Sun; Xin Qi Zhao; Jian Wei Song

Synthesis of hexaallylhexaazaisowurtzitane

Xin Le Li^*, Cheng Hui Sun, Xin Qi Zhao, Jian Wei Song

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In order to explore a new route for the synthesis of CL-20, hexaallylhexaazaisowurtzitane was synthesized by condensation reaction of allylamine with aqueous glyoxal without inert gases protection. Its structure was characterized by FTIR, ¹H NMR and ¹³C NMR. This route has higher yield of 37.1% and easier way than the literature. Hexaallylhexaazaisowurtzitane without benzyl group in the molecule would be a potential nitrolyzable precursor to CL-20.

Original language	English
Pages (from-to)	490-491+514
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	15
Issue number	5
Publication status	Published - Oct 2007

Keywords

CL-20
Hexaallylhexaazaisowurtzitane
Organic chemistry
Synthesis

Cite this

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title = "Synthesis of hexaallylhexaazaisowurtzitane",

abstract = "In order to explore a new route for the synthesis of CL-20, hexaallylhexaazaisowurtzitane was synthesized by condensation reaction of allylamine with aqueous glyoxal without inert gases protection. Its structure was characterized by FTIR, 1H NMR and 13C NMR. This route has higher yield of 37.1% and easier way than the literature. Hexaallylhexaazaisowurtzitane without benzyl group in the molecule would be a potential nitrolyzable precursor to CL-20.",

keywords = "CL-20, Hexaallylhexaazaisowurtzitane, Organic chemistry, Synthesis",

author = "Li, {Xin Le} and Sun, {Cheng Hui} and Zhao, {Xin Qi} and Song, {Jian Wei}",

year = "2007",

month = oct,

language = "English",

volume = "15",

pages = "490--491+514",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "5",

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TY - JOUR

T1 - Synthesis of hexaallylhexaazaisowurtzitane

AU - Li, Xin Le

AU - Sun, Cheng Hui

AU - Zhao, Xin Qi

AU - Song, Jian Wei

PY - 2007/10

Y1 - 2007/10

N2 - In order to explore a new route for the synthesis of CL-20, hexaallylhexaazaisowurtzitane was synthesized by condensation reaction of allylamine with aqueous glyoxal without inert gases protection. Its structure was characterized by FTIR, 1H NMR and 13C NMR. This route has higher yield of 37.1% and easier way than the literature. Hexaallylhexaazaisowurtzitane without benzyl group in the molecule would be a potential nitrolyzable precursor to CL-20.

AB - In order to explore a new route for the synthesis of CL-20, hexaallylhexaazaisowurtzitane was synthesized by condensation reaction of allylamine with aqueous glyoxal without inert gases protection. Its structure was characterized by FTIR, 1H NMR and 13C NMR. This route has higher yield of 37.1% and easier way than the literature. Hexaallylhexaazaisowurtzitane without benzyl group in the molecule would be a potential nitrolyzable precursor to CL-20.

KW - CL-20

KW - Hexaallylhexaazaisowurtzitane

KW - Organic chemistry

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=36348986817&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:36348986817

SN - 1006-9941

VL - 15

SP - 490-491+514

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 5

ER -

Synthesis of hexaallylhexaazaisowurtzitane

Abstract

Keywords

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