Synthesis, crystal structure and magnetic property of a binuclear iron(III) complex with phenol–pyrazole based ligands

Chen Yan Wei; Yuan Zhang; Yu Yu Xie; Rui Zhi Du; Tian Fu Liu

doi:10.1080/15533174.2016.1186059

Synthesis, crystal structure and magnetic property of a binuclear iron(III) complex with phenol–pyrazole based ligands

Chen Yan Wei, Yuan Zhang, Yu Yu Xie, Rui Zhi Du, Tian Fu Liu^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The compound [Fe₂(Hmpp)₄(OMe)₂]_3MeOH (1) (Hmpp D 2-(4-methyl-1H-pyrazol-3-yl)phenol) was characterized by elementary analysis, IR, X-ray crystallography, and magnetic measurements. The X-ray crystallography results reveal that the molecule 1 consists of a binuclear iron(III) natural complex and three methanol molecules. In the complex, two Fe³⁺ions are bridged by two µ₂-OMe. Magnetic measurements indicate that the two Fe³⁺ ions are antiferromagnetically coupled.

Original language	English
Pages (from-to)	401-404
Number of pages	4
Journal	Inorganic and Nano-Metal Chemistry
Volume	47
Issue number	3
DOIs	https://doi.org/10.1080/15533174.2016.1186059
Publication status	Published - 2017

Keywords

Binuclear iron complex
Crystal structure
Magnetic property

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10.1080/15533174.2016.1186059

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title = "Synthesis, crystal structure and magnetic property of a binuclear iron(III) complex with phenol–pyrazole based ligands",

abstract = "The compound [Fe2(Hmpp)4(OMe)2]_3MeOH (1) (Hmpp D 2-(4-methyl-1H-pyrazol-3-yl)phenol) was characterized by elementary analysis, IR, X-ray crystallography, and magnetic measurements. The X-ray crystallography results reveal that the molecule 1 consists of a binuclear iron(III) natural complex and three methanol molecules. In the complex, two Fe3+ions are bridged by two µ2-OMe. Magnetic measurements indicate that the two Fe3+ ions are antiferromagnetically coupled.",

keywords = "Binuclear iron complex, Crystal structure, Magnetic property",

author = "Wei, {Chen Yan} and Yuan Zhang and Xie, {Yu Yu} and Du, {Rui Zhi} and Liu, {Tian Fu}",

note = "Publisher Copyright: {\textcopyright} 2017 Taylor & Francis Group, LLC.",

year = "2017",

doi = "10.1080/15533174.2016.1186059",

language = "English",

volume = "47",

pages = "401--404",

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T1 - Synthesis, crystal structure and magnetic property of a binuclear iron(III) complex with phenol–pyrazole based ligands

AU - Wei, Chen Yan

AU - Zhang, Yuan

AU - Xie, Yu Yu

AU - Du, Rui Zhi

AU - Liu, Tian Fu

PY - 2017

Y1 - 2017

N2 - The compound [Fe2(Hmpp)4(OMe)2]_3MeOH (1) (Hmpp D 2-(4-methyl-1H-pyrazol-3-yl)phenol) was characterized by elementary analysis, IR, X-ray crystallography, and magnetic measurements. The X-ray crystallography results reveal that the molecule 1 consists of a binuclear iron(III) natural complex and three methanol molecules. In the complex, two Fe3+ions are bridged by two µ2-OMe. Magnetic measurements indicate that the two Fe3+ ions are antiferromagnetically coupled.

AB - The compound [Fe2(Hmpp)4(OMe)2]_3MeOH (1) (Hmpp D 2-(4-methyl-1H-pyrazol-3-yl)phenol) was characterized by elementary analysis, IR, X-ray crystallography, and magnetic measurements. The X-ray crystallography results reveal that the molecule 1 consists of a binuclear iron(III) natural complex and three methanol molecules. In the complex, two Fe3+ions are bridged by two µ2-OMe. Magnetic measurements indicate that the two Fe3+ ions are antiferromagnetically coupled.

KW - Binuclear iron complex

KW - Crystal structure

KW - Magnetic property

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AN - SCOPUS:85026801759

SN - 2470-1556

VL - 47

SP - 401

EP - 404

JO - Inorganic and Nano-Metal Chemistry

JF - Inorganic and Nano-Metal Chemistry

IS - 3

ER -

Synthesis, crystal structure and magnetic property of a binuclear iron(III) complex with phenol–pyrazole based ligands

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Keywords

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