Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sand wich Binuclear Iron Carborane Complex Cp′ 2Fe2 (CO)3(Se2C2B10H10)

Shi Xiang Lu; Guo Xin Jin; Ning Hai Hu

Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sand wich Binuclear Iron Carborane Complex Cp′ ₂Fe₂ (CO)₃(Se₂C₂B₁₀H₁₀)

Shi Xiang Lu, Guo Xin Jin^*, Ning Hai Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The half-sandwich methylcyclopentadienyl iron carbonyl complex reacted with 1,2-dilithium diselenolate carborane Li₂Se₂C₂B₁₀H₁₀ (1) which was produced by the insertion of element Se into 1,2-dilithium carborane to give a half-sandwich binuclear iron carborane complex Cp′ ₂Fe₂ (CO)₃Se₂C₂B₁₀H₁₀ (3). X-ray structural analysis of complex 3 reveals that one of the iron atoms is chiral.

Original language	English
Pages (from-to)	1079-1080
Number of pages	2
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	23
Issue number	6
Publication status	Published - Jun 2002
Externally published	Yes

Keywords

Asymmetrical structrure
Carborane
Half-sandwich methylcyclopentadienyl iron carbonyl complex
X-ray molecular structure anylysis

Cite this

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title = "Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sand wich Binuclear Iron Carborane Complex Cp′ 2Fe2 (CO)3(Se2C2B10H10)",

abstract = "The half-sandwich methylcyclopentadienyl iron carbonyl complex reacted with 1,2-dilithium diselenolate carborane Li2Se2C2B10H10 (1) which was produced by the insertion of element Se into 1,2-dilithium carborane to give a half-sandwich binuclear iron carborane complex Cp′ 2Fe2 (CO)3Se2C2B10H10 (3). X-ray structural analysis of complex 3 reveals that one of the iron atoms is chiral.",

keywords = "Asymmetrical structrure, Carborane, Half-sandwich methylcyclopentadienyl iron carbonyl complex, X-ray molecular structure anylysis",

author = "Lu, {Shi Xiang} and Jin, {Guo Xin} and Hu, {Ning Hai}",

year = "2002",

month = jun,

language = "English",

volume = "23",

pages = "1079--1080",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "6",

}

Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sand wich Binuclear Iron Carborane Complex Cp′ ₂Fe₂ (CO)₃(Se₂C₂B₁₀H₁₀). / Lu, Shi Xiang; Jin, Guo Xin; Hu, Ning Hai.
In: Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, Vol. 23, No. 6, 06.2002, p. 1079-1080.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sand wich Binuclear Iron Carborane Complex Cp′ 2Fe2 (CO)3(Se2C2B10H10)

AU - Lu, Shi Xiang

AU - Jin, Guo Xin

AU - Hu, Ning Hai

PY - 2002/6

Y1 - 2002/6

N2 - The half-sandwich methylcyclopentadienyl iron carbonyl complex reacted with 1,2-dilithium diselenolate carborane Li2Se2C2B10H10 (1) which was produced by the insertion of element Se into 1,2-dilithium carborane to give a half-sandwich binuclear iron carborane complex Cp′ 2Fe2 (CO)3Se2C2B10H10 (3). X-ray structural analysis of complex 3 reveals that one of the iron atoms is chiral.

AB - The half-sandwich methylcyclopentadienyl iron carbonyl complex reacted with 1,2-dilithium diselenolate carborane Li2Se2C2B10H10 (1) which was produced by the insertion of element Se into 1,2-dilithium carborane to give a half-sandwich binuclear iron carborane complex Cp′ 2Fe2 (CO)3Se2C2B10H10 (3). X-ray structural analysis of complex 3 reveals that one of the iron atoms is chiral.

KW - Asymmetrical structrure

KW - Carborane

KW - Half-sandwich methylcyclopentadienyl iron carbonyl complex

KW - X-ray molecular structure anylysis

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M3 - Article

AN - SCOPUS:0346638474

SN - 0251-0790

VL - 23

SP - 1079

EP - 1080

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 6

ER -

Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sand wich Binuclear Iron Carborane Complex Cp′ ₂Fe₂ (CO)₃(Se₂C₂B₁₀H₁₀)

Abstract

Keywords

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