Synthesis and surface properties of dihydroxybutyl terminated-polydimethylsiloxane modified polyurethane

Lin Lin Feng; Xing Yuan Zhang; Jia Bing Dai; Zhen Ge; Jing Chao; Chen Yan Bai

Synthesis and surface properties of dihydroxybutyl terminated-polydimethylsiloxane modified polyurethane

Lin Lin Feng^*, Xing Yuan Zhang, Jia Bing Dai, Zhen Ge, Jing Chao, Chen Yan Bai

^*Corresponding author for this work

University of Science and Technology of China

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A series of siloxane-modified polyurethanes (Si-PU) were synthesized based on 2,4-tolylene diisocyanate (TDI), dihydroxybutyl-terminated polydimethylsiloxane (DHPDMS), poly(tetramethylene ether) glycol (PTMG) and 1,4-butanediol (BDO). Fourier transform infrared spectroscopy (FT-IR) analysis shows that DHPDMS has been incorporated into the polyurethane chains. With the increase of the content of DHPDMS, the water contact angle increases while the surface tensile force decreases. When the content of DHPDMS is over 5%, both the water contact angle and the surface tensile force tend to a constant. With the increase of temperature, the contact angle increases, and also tends to a constant when temperature is higher than 50°C. The results indicate that Si-PU reaches good surface and mechanical properties when the content of DHPDMS is about 5%.

Original language	English
Pages (from-to)	47-50
Number of pages	4
Journal	Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
Volume	23
Issue number	3
Publication status	Published - May 2007
Externally published	Yes

Keywords

Contact angle
Dihydroxybutyl-terminated polydimethylsiloxane
Siloxane-modified polyurethane
Surface tensile force

Cite this

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title = "Synthesis and surface properties of dihydroxybutyl terminated-polydimethylsiloxane modified polyurethane",

abstract = "A series of siloxane-modified polyurethanes (Si-PU) were synthesized based on 2,4-tolylene diisocyanate (TDI), dihydroxybutyl-terminated polydimethylsiloxane (DHPDMS), poly(tetramethylene ether) glycol (PTMG) and 1,4-butanediol (BDO). Fourier transform infrared spectroscopy (FT-IR) analysis shows that DHPDMS has been incorporated into the polyurethane chains. With the increase of the content of DHPDMS, the water contact angle increases while the surface tensile force decreases. When the content of DHPDMS is over 5%, both the water contact angle and the surface tensile force tend to a constant. With the increase of temperature, the contact angle increases, and also tends to a constant when temperature is higher than 50°C. The results indicate that Si-PU reaches good surface and mechanical properties when the content of DHPDMS is about 5%.",

keywords = "Contact angle, Dihydroxybutyl-terminated polydimethylsiloxane, Siloxane-modified polyurethane, Surface tensile force",

author = "Feng, {Lin Lin} and Zhang, {Xing Yuan} and Dai, {Jia Bing} and Zhen Ge and Jing Chao and Bai, {Chen Yan}",

year = "2007",

month = may,

language = "English",

volume = "23",

pages = "47--50",

journal = "Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering",

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TY - JOUR

T1 - Synthesis and surface properties of dihydroxybutyl terminated-polydimethylsiloxane modified polyurethane

AU - Feng, Lin Lin

AU - Zhang, Xing Yuan

AU - Dai, Jia Bing

AU - Ge, Zhen

AU - Chao, Jing

AU - Bai, Chen Yan

PY - 2007/5

Y1 - 2007/5

N2 - A series of siloxane-modified polyurethanes (Si-PU) were synthesized based on 2,4-tolylene diisocyanate (TDI), dihydroxybutyl-terminated polydimethylsiloxane (DHPDMS), poly(tetramethylene ether) glycol (PTMG) and 1,4-butanediol (BDO). Fourier transform infrared spectroscopy (FT-IR) analysis shows that DHPDMS has been incorporated into the polyurethane chains. With the increase of the content of DHPDMS, the water contact angle increases while the surface tensile force decreases. When the content of DHPDMS is over 5%, both the water contact angle and the surface tensile force tend to a constant. With the increase of temperature, the contact angle increases, and also tends to a constant when temperature is higher than 50°C. The results indicate that Si-PU reaches good surface and mechanical properties when the content of DHPDMS is about 5%.

AB - A series of siloxane-modified polyurethanes (Si-PU) were synthesized based on 2,4-tolylene diisocyanate (TDI), dihydroxybutyl-terminated polydimethylsiloxane (DHPDMS), poly(tetramethylene ether) glycol (PTMG) and 1,4-butanediol (BDO). Fourier transform infrared spectroscopy (FT-IR) analysis shows that DHPDMS has been incorporated into the polyurethane chains. With the increase of the content of DHPDMS, the water contact angle increases while the surface tensile force decreases. When the content of DHPDMS is over 5%, both the water contact angle and the surface tensile force tend to a constant. With the increase of temperature, the contact angle increases, and also tends to a constant when temperature is higher than 50°C. The results indicate that Si-PU reaches good surface and mechanical properties when the content of DHPDMS is about 5%.

KW - Contact angle

KW - Dihydroxybutyl-terminated polydimethylsiloxane

KW - Siloxane-modified polyurethane

KW - Surface tensile force

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AN - SCOPUS:34347212884

SN - 1000-7555

VL - 23

SP - 47

EP - 50

JO - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

JF - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

IS - 3

ER -

Synthesis and surface properties of dihydroxybutyl terminated-polydimethylsiloxane modified polyurethane

Abstract

Keywords

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