Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba- closo-dodecaborane [Li(THF)4][Fe(S2C2B 10H10)2(THF)]

Shi Xiang Lu; Guo Xin Jin; Ning Hai Hu

Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba- closo-dodecaborane [Li(THF)₄][Fe(S₂C₂B ₁₀H₁₀)₂(THF)]

Shi Xiang Lu, Guo Xin Jin^*, Ning Hai Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The crystal of complex [Li(THF)₄][Fe(S₂C ₂B₁₀H₁₀)₂(THF)] 3 belongs to monoclinic, space group P2₁ with a = 11.964(2), b = 16.527(3), c = 12.554(3) Å, β = 108.70(3)°, V = 2351.3(8) Å³, Z = 2, M_r = 835.95, D_c = 1.181 g/cm³, μ(MoKα) = 5.30 cm^-1, F(000) = 874, R = 0.0622 and Rw = 0.1538 for 1641 observed reflections with I > 2σ(I). The ionic complex of 3 contains the square pyramidal anion of [Fe(S₂C₂B ₁₀H₁₀)₂(THF)]^- and the tetrahedral cation of [Li(THF)₄]⁺. The iron is 5-coordinated and located in the square pyramidal configuration. The iron atom and the four sulfur atoms are almost coplanar. The Lithium atom is coordinated with four oxygen atoms of four THF molecules and located in a tetrahedral configuration.

Original language	English
Pages (from-to)	493-496
Number of pages	4
Journal	Jiegou Huaxue
Volume	21
Issue number	5
Publication status	Published - 2002
Externally published	Yes

Keywords

Crystal structure
Dithiolate carborane
Iron complex

Cite this

@article{42e4e0824ca3493bb0a1e5a5d6166af4,

title = "Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba- closo-dodecaborane [Li(THF)4][Fe(S2C2B 10H10)2(THF)]",

abstract = "The crystal of complex [Li(THF)4][Fe(S2C 2B10H10)2(THF)] 3 belongs to monoclinic, space group P21 with a = 11.964(2), b = 16.527(3), c = 12.554(3) {\AA}, β = 108.70(3)°, V = 2351.3(8) {\AA}3, Z = 2, Mr = 835.95, Dc = 1.181 g/cm3, μ(MoKα) = 5.30 cm-1, F(000) = 874, R = 0.0622 and Rw = 0.1538 for 1641 observed reflections with I > 2σ(I). The ionic complex of 3 contains the square pyramidal anion of [Fe(S2C2B 10H10)2(THF)]- and the tetrahedral cation of [Li(THF)4]+. The iron is 5-coordinated and located in the square pyramidal configuration. The iron atom and the four sulfur atoms are almost coplanar. The Lithium atom is coordinated with four oxygen atoms of four THF molecules and located in a tetrahedral configuration.",

keywords = "Crystal structure, Dithiolate carborane, Iron complex",

author = "Lu, {Shi Xiang} and Jin, {Guo Xin} and Hu, {Ning Hai}",

year = "2002",

language = "English",

volume = "21",

pages = "493--496",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "5",

}

TY - JOUR

T1 - Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba- closo-dodecaborane [Li(THF)4][Fe(S2C2B 10H10)2(THF)]

AU - Lu, Shi Xiang

AU - Jin, Guo Xin

AU - Hu, Ning Hai

PY - 2002

Y1 - 2002

N2 - The crystal of complex [Li(THF)4][Fe(S2C 2B10H10)2(THF)] 3 belongs to monoclinic, space group P21 with a = 11.964(2), b = 16.527(3), c = 12.554(3) Å, β = 108.70(3)°, V = 2351.3(8) Å3, Z = 2, Mr = 835.95, Dc = 1.181 g/cm3, μ(MoKα) = 5.30 cm-1, F(000) = 874, R = 0.0622 and Rw = 0.1538 for 1641 observed reflections with I > 2σ(I). The ionic complex of 3 contains the square pyramidal anion of [Fe(S2C2B 10H10)2(THF)]- and the tetrahedral cation of [Li(THF)4]+. The iron is 5-coordinated and located in the square pyramidal configuration. The iron atom and the four sulfur atoms are almost coplanar. The Lithium atom is coordinated with four oxygen atoms of four THF molecules and located in a tetrahedral configuration.

AB - The crystal of complex [Li(THF)4][Fe(S2C 2B10H10)2(THF)] 3 belongs to monoclinic, space group P21 with a = 11.964(2), b = 16.527(3), c = 12.554(3) Å, β = 108.70(3)°, V = 2351.3(8) Å3, Z = 2, Mr = 835.95, Dc = 1.181 g/cm3, μ(MoKα) = 5.30 cm-1, F(000) = 874, R = 0.0622 and Rw = 0.1538 for 1641 observed reflections with I > 2σ(I). The ionic complex of 3 contains the square pyramidal anion of [Fe(S2C2B 10H10)2(THF)]- and the tetrahedral cation of [Li(THF)4]+. The iron is 5-coordinated and located in the square pyramidal configuration. The iron atom and the four sulfur atoms are almost coplanar. The Lithium atom is coordinated with four oxygen atoms of four THF molecules and located in a tetrahedral configuration.

KW - Crystal structure

KW - Dithiolate carborane

KW - Iron complex

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M3 - Article

AN - SCOPUS:23044532431

SN - 0254-5861

VL - 21

SP - 493

EP - 496

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 5

ER -

Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba- closo-dodecaborane [Li(THF)₄][Fe(S₂C₂B ₁₀H₁₀)₂(THF)]

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