Synthesis and structure of Ag3PSe4

Hong Wei Ma; Guo Cong Guo; Wen Tong Chen; Lei Deng; Guo Wei Zhou; Zhen Chao Dong; Jin Shun Huang

Synthesis and structure of Ag₃PSe₄

Hong Wei Ma, Guo Cong Guo^*, Wen Tong Chen, Lei Deng, Guo Wei Zhou, Zhen Chao Dong, Jin Shun Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The title compound Ag₃PSe₄ was synthesized by the reaction of Ag powder, P₂Se₅ and Se in a molar ratio of 1:1:1 at 500°C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn2₁ with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) Å, V = 326.7(3) Å³, Z = 2, D_c = 6.816 g/cm³, M_r = 670.42, F(000) = 584, μ = 31.302 mm^-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.

Original language	English
Pages (from-to)	161-164
Number of pages	4
Journal	Jiegou Huaxue
Volume	22
Issue number	2
Publication status	Published - 2003
Externally published	Yes

Keywords

Metal chalcogenophosphide
Normal tetrahedral structure
Solid state reaction

Cite this

@article{644e87b28c55419eb30b9cec3423b359,

title = "Synthesis and structure of Ag3PSe4",

abstract = "The title compound Ag3PSe4 was synthesized by the reaction of Ag powder, P2Se5 and Se in a molar ratio of 1:1:1 at 500°C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) {\AA}, V = 326.7(3) {\AA}3, Z = 2, Dc = 6.816 g/cm3, Mr = 670.42, F(000) = 584, μ = 31.302 mm-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.",

keywords = "Metal chalcogenophosphide, Normal tetrahedral structure, Solid state reaction",

author = "Ma, {Hong Wei} and Guo, {Guo Cong} and Chen, {Wen Tong} and Lei Deng and Zhou, {Guo Wei} and Dong, {Zhen Chao} and Huang, {Jin Shun}",

year = "2003",

language = "English",

volume = "22",

pages = "161--164",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "2",

}

TY - JOUR

T1 - Synthesis and structure of Ag3PSe4

AU - Ma, Hong Wei

AU - Guo, Guo Cong

AU - Chen, Wen Tong

AU - Deng, Lei

AU - Zhou, Guo Wei

AU - Dong, Zhen Chao

AU - Huang, Jin Shun

PY - 2003

Y1 - 2003

N2 - The title compound Ag3PSe4 was synthesized by the reaction of Ag powder, P2Se5 and Se in a molar ratio of 1:1:1 at 500°C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) Å, V = 326.7(3) Å3, Z = 2, Dc = 6.816 g/cm3, Mr = 670.42, F(000) = 584, μ = 31.302 mm-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.

AB - The title compound Ag3PSe4 was synthesized by the reaction of Ag powder, P2Se5 and Se in a molar ratio of 1:1:1 at 500°C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) Å, V = 326.7(3) Å3, Z = 2, Dc = 6.816 g/cm3, Mr = 670.42, F(000) = 584, μ = 31.302 mm-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.

KW - Metal chalcogenophosphide

KW - Normal tetrahedral structure

KW - Solid state reaction

UR - http://www.scopus.com/inward/record.url?scp=0038717115&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0038717115

SN - 0254-5861

VL - 22

SP - 161

EP - 164

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 2

ER -

Synthesis and structure of Ag₃PSe₄

Abstract

Keywords

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