Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels

C. Wang; J. Li; Y. Wang; K. Wang; J. Yu; R. Xu

doi:10.1016/s0167-2991(04)80921-2

Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels

C. Wang^*, J. Li, Y. Wang, K. Wang, J. Yu, R. Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

Abstract

A new three-dimensional zinc phosphate [Zn₆P₅O ₂₀]^3-·[C₆N₃H ₁₅]³⁺ ·H₂O (1) has been hydrothermally synthesized from a reaction system Zn(OAc)₂-1-(2-aminoethyl) piperazine-H₃PO₄-H₂O. Single crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15) with a=20.240(4), b=16.856(3), c=8.1541(16)Å, β=111.02(3)°, V=2596.7(9)Å³ and Z=4. Its structure consists of one dimensional 12-membered ring channels along the [001] direction.

Original language	English
Pages (from-to)	1035-1040
Number of pages	6
Journal	Studies in Surface Science and Catalysis
Volume	154 A
DOIs	https://doi.org/10.1016/s0167-2991(04)80921-2
Publication status	Published - 2004
Externally published	Yes

Keywords

Hydrothermal synthesis
Open framework
Structure
Zinc phosphate

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10.1016/s0167-2991(04)80921-2

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@article{14434d2c64b648159dd669d2a8b7c148,

title = "Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels",

abstract = "A new three-dimensional zinc phosphate [Zn6P5O 20]3-·[C6N3H 15]3+ ·H2O (1) has been hydrothermally synthesized from a reaction system Zn(OAc)2-1-(2-aminoethyl) piperazine-H3PO4-H2O. Single crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15) with a=20.240(4), b=16.856(3), c=8.1541(16){\AA}, β=111.02(3)°, V=2596.7(9){\AA}3 and Z=4. Its structure consists of one dimensional 12-membered ring channels along the [001] direction.",

keywords = "Hydrothermal synthesis, Open framework, Structure, Zinc phosphate",

author = "C. Wang and J. Li and Y. Wang and K. Wang and J. Yu and R. Xu",

year = "2004",

doi = "10.1016/s0167-2991(04)80921-2",

language = "English",

volume = "154 A",

pages = "1035--1040",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

}

TY - JOUR

T1 - Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels

AU - Wang, C.

AU - Li, J.

AU - Wang, Y.

AU - Wang, K.

AU - Yu, J.

AU - Xu, R.

PY - 2004

Y1 - 2004

N2 - A new three-dimensional zinc phosphate [Zn6P5O 20]3-·[C6N3H 15]3+ ·H2O (1) has been hydrothermally synthesized from a reaction system Zn(OAc)2-1-(2-aminoethyl) piperazine-H3PO4-H2O. Single crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15) with a=20.240(4), b=16.856(3), c=8.1541(16)Å, β=111.02(3)°, V=2596.7(9)Å3 and Z=4. Its structure consists of one dimensional 12-membered ring channels along the [001] direction.

AB - A new three-dimensional zinc phosphate [Zn6P5O 20]3-·[C6N3H 15]3+ ·H2O (1) has been hydrothermally synthesized from a reaction system Zn(OAc)2-1-(2-aminoethyl) piperazine-H3PO4-H2O. Single crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15) with a=20.240(4), b=16.856(3), c=8.1541(16)Å, β=111.02(3)°, V=2596.7(9)Å3 and Z=4. Its structure consists of one dimensional 12-membered ring channels along the [001] direction.

KW - Hydrothermal synthesis

KW - Open framework

KW - Structure

KW - Zinc phosphate

UR - http://www.scopus.com/inward/record.url?scp=11844284779&partnerID=8YFLogxK

U2 - 10.1016/s0167-2991(04)80921-2

DO - 10.1016/s0167-2991(04)80921-2

M3 - Article

AN - SCOPUS:11844284779

SN - 0167-2991

VL - 154 A

SP - 1035

EP - 1040

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels

Abstract

Keywords

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