TY - JOUR
T1 - Synthesis and performance studies of 1,5-diaminotetrazolium nitrate
AU - Han, Zhiyue
AU - Du, Zhiming
AU - Zhao, Zhihua
AU - Meng, Lingqiao
AU - Zhao, Linshuang
AU - Cong, Xiaomin
N1 - Publisher Copyright:
© 2014 Akadémiai Kiadó, Budapest, Hungary.
PY - 2014/12
Y1 - 2014/12
N2 - 1,5-Diaminotetrazolium nitrate (HDATN) was synthesized with 1,5-diaminotetrazole (DAT) as the raw material. The maximum yield of HDATN was 95.3 %. The structure was characterized by elemental analysis, infrared spectrum, nuclear magnetic resonance spectrum and mass spectrum, and the possible fragmentation mechanism was discussed. The morphology was analyzed by SEM. The thermal stability of HDATN was investigated by TG-DSC and DTA techniques. The kinetic parameters including activation energy and pro-exponential factor were calculated by Kissinger equation. The performance of combustion, combustion heat, and formation enthalpy of HDATN were measured. The detonation products of HDATN were most nitrogen, which were analyzed by gas chromatograph and smoke analyzer. The density, formation heat, detonation pressure, and detonation velocity of HDATN were calculated. It exhibited prospective application in environmentally friendly gas generant and explosion field.
AB - 1,5-Diaminotetrazolium nitrate (HDATN) was synthesized with 1,5-diaminotetrazole (DAT) as the raw material. The maximum yield of HDATN was 95.3 %. The structure was characterized by elemental analysis, infrared spectrum, nuclear magnetic resonance spectrum and mass spectrum, and the possible fragmentation mechanism was discussed. The morphology was analyzed by SEM. The thermal stability of HDATN was investigated by TG-DSC and DTA techniques. The kinetic parameters including activation energy and pro-exponential factor were calculated by Kissinger equation. The performance of combustion, combustion heat, and formation enthalpy of HDATN were measured. The detonation products of HDATN were most nitrogen, which were analyzed by gas chromatograph and smoke analyzer. The density, formation heat, detonation pressure, and detonation velocity of HDATN were calculated. It exhibited prospective application in environmentally friendly gas generant and explosion field.
KW - 1,5-Diaminotetrazolium nitrate
KW - Energetic ionic salt
KW - Nitrogen-rich compound
KW - Performance
KW - Synthesis process optimization
UR - http://www.scopus.com/inward/record.url?scp=85027953571&partnerID=8YFLogxK
U2 - 10.1007/s10973-014-4057-z
DO - 10.1007/s10973-014-4057-z
M3 - Article
AN - SCOPUS:85027953571
SN - 1388-6150
VL - 118
SP - 1493
EP - 1504
JO - Journal of Thermal Analysis and Calorimetry
JF - Journal of Thermal Analysis and Calorimetry
IS - 3
ER -