Synthesis and magnetic properties of a new hexanuclear iron(III) compound

Guo Min Wang; Rong Jia Wei; Li Li Hu; Xiao Jun Sun; Rong Bin Huang; Lan Sun Zheng; Jun Tao

doi:10.1016/j.inoche.2009.05.005

Synthesis and magnetic properties of a new hexanuclear iron(III) compound

Guo Min Wang, Rong Jia Wei, Li Li Hu, Xiao Jun Sun^*, Rong Bin Huang, Lan Sun Zheng, Jun Tao

^*Corresponding author for this work

Xiamen University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A hexanuclear Fe(III) compound with new core topology, [Fe₆(OMe)₂(DHMP)₄(AD)₂] (1, H₃DHMP = (E)-2-((1,3-dihydroxy-2-methylpropan-2-ylimino)methyl)phenol, H₂AD = adipic acid), is reported. The hexanuclear Fe(III) core can be viewed as two Fe₃(DHMP)₂ units connected through double μ₂-OMe^- bridges, featuring adjacent Fe···Fe distances of 3.105 and 3.109 Å within unit and 3.111 Å between units, respectively. Variable temperature magnetic studies indicate antiferromagnetic exchanges between adjacent Fe(III) ions and which mediated by μ₂-OMe^- bridges is stronger than those by DHMP alkoxo bridges. Magnetic-structural correlation is also proposed.

Original language	English
Pages (from-to)	622-624
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2009.05.005
Publication status	Published - Jul 2009
Externally published	Yes

Keywords

Antiferromagnetic
Crystal structure
Hexanuclear
Iron(III)
Synthesis

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10.1016/j.inoche.2009.05.005

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@article{f80430cbd48c4e5191d918a2db20192d,

title = "Synthesis and magnetic properties of a new hexanuclear iron(III) compound",

abstract = "A hexanuclear Fe(III) compound with new core topology, [Fe6(OMe)2(DHMP)4(AD)2] (1, H3DHMP = (E)-2-((1,3-dihydroxy-2-methylpropan-2-ylimino)methyl)phenol, H2AD = adipic acid), is reported. The hexanuclear Fe(III) core can be viewed as two Fe3(DHMP)2 units connected through double μ2-OMe- bridges, featuring adjacent Fe···Fe distances of 3.105 and 3.109 {\AA} within unit and 3.111 {\AA} between units, respectively. Variable temperature magnetic studies indicate antiferromagnetic exchanges between adjacent Fe(III) ions and which mediated by μ2-OMe- bridges is stronger than those by DHMP alkoxo bridges. Magnetic-structural correlation is also proposed.",

keywords = "Antiferromagnetic, Crystal structure, Hexanuclear, Iron(III), Synthesis",

author = "Wang, {Guo Min} and Wei, {Rong Jia} and Hu, {Li Li} and Sun, {Xiao Jun} and Huang, {Rong Bin} and Zheng, {Lan Sun} and Jun Tao",

year = "2009",

month = jul,

doi = "10.1016/j.inoche.2009.05.005",

language = "English",

volume = "12",

pages = "622--624",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Synthesis and magnetic properties of a new hexanuclear iron(III) compound

AU - Wang, Guo Min

AU - Wei, Rong Jia

AU - Hu, Li Li

AU - Sun, Xiao Jun

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Tao, Jun

PY - 2009/7

Y1 - 2009/7

N2 - A hexanuclear Fe(III) compound with new core topology, [Fe6(OMe)2(DHMP)4(AD)2] (1, H3DHMP = (E)-2-((1,3-dihydroxy-2-methylpropan-2-ylimino)methyl)phenol, H2AD = adipic acid), is reported. The hexanuclear Fe(III) core can be viewed as two Fe3(DHMP)2 units connected through double μ2-OMe- bridges, featuring adjacent Fe···Fe distances of 3.105 and 3.109 Å within unit and 3.111 Å between units, respectively. Variable temperature magnetic studies indicate antiferromagnetic exchanges between adjacent Fe(III) ions and which mediated by μ2-OMe- bridges is stronger than those by DHMP alkoxo bridges. Magnetic-structural correlation is also proposed.

AB - A hexanuclear Fe(III) compound with new core topology, [Fe6(OMe)2(DHMP)4(AD)2] (1, H3DHMP = (E)-2-((1,3-dihydroxy-2-methylpropan-2-ylimino)methyl)phenol, H2AD = adipic acid), is reported. The hexanuclear Fe(III) core can be viewed as two Fe3(DHMP)2 units connected through double μ2-OMe- bridges, featuring adjacent Fe···Fe distances of 3.105 and 3.109 Å within unit and 3.111 Å between units, respectively. Variable temperature magnetic studies indicate antiferromagnetic exchanges between adjacent Fe(III) ions and which mediated by μ2-OMe- bridges is stronger than those by DHMP alkoxo bridges. Magnetic-structural correlation is also proposed.

KW - Antiferromagnetic

KW - Crystal structure

KW - Hexanuclear

KW - Iron(III)

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=67649363323&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2009.05.005

DO - 10.1016/j.inoche.2009.05.005

M3 - Article

AN - SCOPUS:67649363323

SN - 1387-7003

VL - 12

SP - 622

EP - 624

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Synthesis and magnetic properties of a new hexanuclear iron(III) compound

Abstract

Keywords

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