Synthesis and infrared spectroscopic study of 1-D magnetic chain compound based on [BrBzPy][Ni(dmit)2]

You Cun Chen; Qing Hai Shu

Synthesis and infrared spectroscopic study of 1-D magnetic chain compound based on [BrBzPy][Ni(dmit)₂]

You Cun Chen^*, Qing Hai Shu

^*Corresponding author for this work

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high T_c molecule ferromagnet. A new compound [BrBzPy] [Ni(dmit)₂] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P2₁/c a = 0.6275(1) ran, b = 1.7438(3) nm, c = 2.2839(3) ran, α = 90°, β = 91.87(1)°, γ = 90°, V = 2.497(7) nm³, Z = 4, Mr = 700.57, and Dc = 1.863 g·cm^-3. The planar [Ni(dmit)₂]^- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.

Original language	English
Pages (from-to)	54-56
Number of pages	3
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	26
Issue number	1
Publication status	Published - Jan 2006
Externally published	Yes

Keywords

Dmit
Infrared spectra
Molecular magnets
Structure characterization

Cite this

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title = "Synthesis and infrared spectroscopic study of 1-D magnetic chain compound based on [BrBzPy][Ni(dmit)2]",

abstract = "The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high Tc molecule ferromagnet. A new compound [BrBzPy] [Ni(dmit)2] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P21/c a = 0.6275(1) ran, b = 1.7438(3) nm, c = 2.2839(3) ran, α = 90°, β = 91.87(1)°, γ = 90°, V = 2.497(7) nm3, Z = 4, Mr = 700.57, and Dc = 1.863 g·cm-3. The planar [Ni(dmit)2]- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.",

keywords = "Dmit, Infrared spectra, Molecular magnets, Structure characterization",

author = "Chen, {You Cun} and Shu, {Qing Hai}",

year = "2006",

month = jan,

language = "English",

volume = "26",

pages = "54--56",

journal = "Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis",

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T1 - Synthesis and infrared spectroscopic study of 1-D magnetic chain compound based on [BrBzPy][Ni(dmit)2]

AU - Chen, You Cun

AU - Shu, Qing Hai

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Y1 - 2006/1

N2 - The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high Tc molecule ferromagnet. A new compound [BrBzPy] [Ni(dmit)2] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P21/c a = 0.6275(1) ran, b = 1.7438(3) nm, c = 2.2839(3) ran, α = 90°, β = 91.87(1)°, γ = 90°, V = 2.497(7) nm3, Z = 4, Mr = 700.57, and Dc = 1.863 g·cm-3. The planar [Ni(dmit)2]- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.

AB - The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high Tc molecule ferromagnet. A new compound [BrBzPy] [Ni(dmit)2] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P21/c a = 0.6275(1) ran, b = 1.7438(3) nm, c = 2.2839(3) ran, α = 90°, β = 91.87(1)°, γ = 90°, V = 2.497(7) nm3, Z = 4, Mr = 700.57, and Dc = 1.863 g·cm-3. The planar [Ni(dmit)2]- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.

KW - Dmit

KW - Infrared spectra

KW - Molecular magnets

KW - Structure characterization

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M3 - Article

AN - SCOPUS:32844464080

SN - 1000-0593

VL - 26

SP - 54

EP - 56

JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

IS - 1

ER -

Synthesis and infrared spectroscopic study of 1-D magnetic chain compound based on [BrBzPy][Ni(dmit)₂]

Abstract

Keywords

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