Synthesis and Improved Properties of Hypergolic Boronium-Based Ionic Liquids

Xingye Li; Huijie Lu; Qi Wang; Jinglun Huang; Fude Nie; Haibo Li; Fu Xue Chen

doi:10.1002/cjoc.201600048

Synthesis and Improved Properties of Hypergolic Boronium-Based Ionic Liquids

Xingye Li, Huijie Lu, Qi Wang, Jinglun Huang, Fude Nie, Haibo Li, Fu Xue Chen^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A series of asymmetric monoimidazolium dihydroboronium-based ionic liquids (ILs) were synthesized from amine-boranes. All the resulting ILs were fully characterized by¹H and¹³C NMR, IR spectroscopy, elemental analysis or high resolution mass spectrum. Compared with the symmetric bisimidazolium dihydroboronium-based ILs, these new ILs exhibited improved properties with shorter ignition delay times (IDs), higher densities, and lower phase transition temperature showing the promising application potential as green propellants.

Original language	English
Pages (from-to)	709-714
Number of pages	6
Journal	Chinese Journal of Chemistry
Volume	34
Issue number	7
DOIs	https://doi.org/10.1002/cjoc.201600048
Publication status	Published - Jul 2016

Keywords

boranes
hypergolic
ignition delay times
ionic liquids
propellants

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10.1002/cjoc.201600048

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title = "Synthesis and Improved Properties of Hypergolic Boronium-Based Ionic Liquids",

abstract = "A series of asymmetric monoimidazolium dihydroboronium-based ionic liquids (ILs) were synthesized from amine-boranes. All the resulting ILs were fully characterized by1H and13C NMR, IR spectroscopy, elemental analysis or high resolution mass spectrum. Compared with the symmetric bisimidazolium dihydroboronium-based ILs, these new ILs exhibited improved properties with shorter ignition delay times (IDs), higher densities, and lower phase transition temperature showing the promising application potential as green propellants.",

keywords = "boranes, hypergolic, ignition delay times, ionic liquids, propellants",

author = "Xingye Li and Huijie Lu and Qi Wang and Jinglun Huang and Fude Nie and Haibo Li and Chen, {Fu Xue}",

note = "Publisher Copyright: Copyright {\textcopyright} 2016 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

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T1 - Synthesis and Improved Properties of Hypergolic Boronium-Based Ionic Liquids

AU - Li, Xingye

AU - Lu, Huijie

AU - Wang, Qi

AU - Huang, Jinglun

AU - Nie, Fude

AU - Li, Haibo

AU - Chen, Fu Xue

PY - 2016/7

Y1 - 2016/7

N2 - A series of asymmetric monoimidazolium dihydroboronium-based ionic liquids (ILs) were synthesized from amine-boranes. All the resulting ILs were fully characterized by1H and13C NMR, IR spectroscopy, elemental analysis or high resolution mass spectrum. Compared with the symmetric bisimidazolium dihydroboronium-based ILs, these new ILs exhibited improved properties with shorter ignition delay times (IDs), higher densities, and lower phase transition temperature showing the promising application potential as green propellants.

AB - A series of asymmetric monoimidazolium dihydroboronium-based ionic liquids (ILs) were synthesized from amine-boranes. All the resulting ILs were fully characterized by1H and13C NMR, IR spectroscopy, elemental analysis or high resolution mass spectrum. Compared with the symmetric bisimidazolium dihydroboronium-based ILs, these new ILs exhibited improved properties with shorter ignition delay times (IDs), higher densities, and lower phase transition temperature showing the promising application potential as green propellants.

KW - boranes

KW - hypergolic

KW - ignition delay times

KW - ionic liquids

KW - propellants

UR - http://www.scopus.com/inward/record.url?scp=84961828606&partnerID=8YFLogxK

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DO - 10.1002/cjoc.201600048

M3 - Article

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SP - 709

EP - 714

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 7

ER -

Synthesis and Improved Properties of Hypergolic Boronium-Based Ionic Liquids

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