Synthesis and electrospinning carboxymethyl cellulose lithium (CMC-Li) modified 9,10-anthraquinone (AQ) high-rate lithium-ion battery

Lei Qiu, Ziqiang Shao*, Minglong Liu, Jianquan Wang, Pengfa Li, Ming Zhao

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

New cellulose derivative CMC-Li was synthesized, and nanometer CMC-Li fiber was applied to lithium-ion battery and coated with AQ by electrospinning. Under the protection of inert gas, modified AQ/carbon nanofibers (CNF)/Li nanometer composite material was obtained by carbonization in 280 C as lithium battery anode materials for the first time. The morphologies and structures performance of materials were characterized by using IR, 1H NMR, SEM, CV and EIS, respectively. Specific capacity was increased from 197 to 226.4 mAh g -1 after modification for the first discharge at the rate of 2C. Irreversible reduction reaction peaks of modified material appeared between 1.5 and 1.7 V and the lowest oxidation reduction peak of the difference were 0.42 V, the polarization was weaker. Performance of cell with CMC-Li with the high degree of substitution (DS) was superior to that with low DS. Cellulose materials were applied to lithium battery to improve battery performance by electrospinning.

Original languageEnglish
Pages (from-to)986-992
Number of pages7
JournalCarbohydrate Polymers
Volume102
Issue number1
DOIs
Publication statusPublished - 15 Feb 2014

Keywords

  • Anode materials AQ
  • CMC-Li
  • Cellulose derivatives
  • Electrospinning
  • Lithium-ion battery

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