Synthesis and crystal structure of potassium triaqua(ethyleneamin-N, N, N′, N′-tetraacetate)gadolinium(III) pentahydrate

Chun Yang; Guo Cong Guo; Guo Wei Zhou; Fa Kun Zheng; Jia Cheng Liu; Hong Wei Ma; Ming Sheng Wang; Jin Shun Huang

Synthesis and crystal structure of potassium triaqua(ethyleneamin-N, N, N′, N′-tetraacetate)gadolinium(III) pentahydrate

Chun Yang, Guo Cong Guo^*, Guo Wei Zhou, Fa Kun Zheng, Jia Cheng Liu, Hong Wei Ma, Ming Sheng Wang, Jin Shun Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The potassium triaqua(ethylenediamine-tetraacetate)gadolinium (III) pentahydrate, K[Gd(Edta)(H₂O)₃]·5H₂O, has been synthesized and structurally characterized. It crystallizes in orthorhombic, space group Fdd2 with a = 19.8851(6), b = 36.078(1), c = 12.2306(4) Å, V = 8774.3(5) Å³, Z = 16, D_c = 1.904 g/cm³, M_r = 628.69, μ= 3.290 mm^-1, F(000) = 5008, the final R = 0.0293 and wR = 0.0763 for 3314 observed reflections with I > 2ω(I). The Gd atom in the title compound is nine-coordinate through four O atoms and two N atoms in ethylenediamine- tetraacetate, and three O atoms of water.

Original language	English
Pages (from-to)	364-367
Number of pages	4
Journal	Jiegou Huaxue
Volume	21
Issue number	4
Publication status	Published - 2002
Externally published	Yes

Keywords

Crystal structure
Edta complex
Lanthanide complex

Cite this

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title = "Synthesis and crystal structure of potassium triaqua(ethyleneamin-N, N, N′, N′-tetraacetate)gadolinium(III) pentahydrate",

abstract = "The potassium triaqua(ethylenediamine-tetraacetate)gadolinium (III) pentahydrate, K[Gd(Edta)(H2O)3]·5H2O, has been synthesized and structurally characterized. It crystallizes in orthorhombic, space group Fdd2 with a = 19.8851(6), b = 36.078(1), c = 12.2306(4) {\AA}, V = 8774.3(5) {\AA}3, Z = 16, Dc = 1.904 g/cm3, Mr = 628.69, μ= 3.290 mm-1, F(000) = 5008, the final R = 0.0293 and wR = 0.0763 for 3314 observed reflections with I > 2ω(I). The Gd atom in the title compound is nine-coordinate through four O atoms and two N atoms in ethylenediamine- tetraacetate, and three O atoms of water.",

keywords = "Crystal structure, Edta complex, Lanthanide complex",

author = "Chun Yang and Guo, {Guo Cong} and Zhou, {Guo Wei} and Zheng, {Fa Kun} and Liu, {Jia Cheng} and Ma, {Hong Wei} and Wang, {Ming Sheng} and Huang, {Jin Shun}",

year = "2002",

language = "English",

volume = "21",

pages = "364--367",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "4",

}

TY - JOUR

T1 - Synthesis and crystal structure of potassium triaqua(ethyleneamin-N, N, N′, N′-tetraacetate)gadolinium(III) pentahydrate

AU - Yang, Chun

AU - Guo, Guo Cong

AU - Zhou, Guo Wei

AU - Zheng, Fa Kun

AU - Liu, Jia Cheng

AU - Ma, Hong Wei

AU - Wang, Ming Sheng

AU - Huang, Jin Shun

PY - 2002

Y1 - 2002

N2 - The potassium triaqua(ethylenediamine-tetraacetate)gadolinium (III) pentahydrate, K[Gd(Edta)(H2O)3]·5H2O, has been synthesized and structurally characterized. It crystallizes in orthorhombic, space group Fdd2 with a = 19.8851(6), b = 36.078(1), c = 12.2306(4) Å, V = 8774.3(5) Å3, Z = 16, Dc = 1.904 g/cm3, Mr = 628.69, μ= 3.290 mm-1, F(000) = 5008, the final R = 0.0293 and wR = 0.0763 for 3314 observed reflections with I > 2ω(I). The Gd atom in the title compound is nine-coordinate through four O atoms and two N atoms in ethylenediamine- tetraacetate, and three O atoms of water.

AB - The potassium triaqua(ethylenediamine-tetraacetate)gadolinium (III) pentahydrate, K[Gd(Edta)(H2O)3]·5H2O, has been synthesized and structurally characterized. It crystallizes in orthorhombic, space group Fdd2 with a = 19.8851(6), b = 36.078(1), c = 12.2306(4) Å, V = 8774.3(5) Å3, Z = 16, Dc = 1.904 g/cm3, Mr = 628.69, μ= 3.290 mm-1, F(000) = 5008, the final R = 0.0293 and wR = 0.0763 for 3314 observed reflections with I > 2ω(I). The Gd atom in the title compound is nine-coordinate through four O atoms and two N atoms in ethylenediamine- tetraacetate, and three O atoms of water.

KW - Crystal structure

KW - Edta complex

KW - Lanthanide complex

UR - http://www.scopus.com/inward/record.url?scp=33750353075&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33750353075

SN - 0254-5861

VL - 21

SP - 364

EP - 367

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 4

ER -

Synthesis and crystal structure of potassium triaqua(ethyleneamin-N, N, N′, N′-tetraacetate)gadolinium(III) pentahydrate

Abstract

Keywords

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