Synthesis and characterization of ZrS3 nanocrystallites

Liying Huang; Kaibin Tang; Qing Yang; Guozhen Shen; Shaojin Jia

doi:10.1016/j.materresbull.2004.02.019

Synthesis and characterization of ZrS₃ nanocrystallites

Liying Huang, Kaibin Tang^*, Qing Yang, Guozhen Shen, Shaojin Jia

^*Corresponding author for this work

University of Science and Technology of China

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

ZrS₃ nanocrystallites have been synthesized via a solvothermal route by the reaction between ZrCl₄ and thiourea at relatively low temperature. The product was characterized by X-ray diffraction (XRD), transmission electron microscope, X-ray fluorescence, Raman spectrum, and photoluminescence (PL). X-ray diffraction pattern shows the monoclinic cell of ZrS₃ with the lattice constants a = 5.128 Å, b = 3.611 Å, c = 9.012 Å, β = 97.13°. The result of X-ray fluorescence gives a Zr(Hf):S mole ratio 1:2.97. The Raman spectrum of the ZrS₃ nanocrystallites has a slightly red shift in comparison with that of ZrS ₃ single crystals. The room temperature photoluminescence of ZrS ₃ nanocrystallites is also reported.

Original language	English
Pages (from-to)	1083-1089
Number of pages	7
Journal	Materials Research Bulletin
Volume	39
Issue number	7-8
DOIs	https://doi.org/10.1016/j.materresbull.2004.02.019
Publication status	Published - 8 Jun 2004
Externally published	Yes

Keywords

A. Inorganic compounds
B. Chemical synthesis
C. X-ray diffraction

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10.1016/j.materresbull.2004.02.019

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@article{298ba0d3f3464282b51dd0a9018fe5fb,

title = "Synthesis and characterization of ZrS3 nanocrystallites",

abstract = "ZrS3 nanocrystallites have been synthesized via a solvothermal route by the reaction between ZrCl4 and thiourea at relatively low temperature. The product was characterized by X-ray diffraction (XRD), transmission electron microscope, X-ray fluorescence, Raman spectrum, and photoluminescence (PL). X-ray diffraction pattern shows the monoclinic cell of ZrS3 with the lattice constants a = 5.128 {\AA}, b = 3.611 {\AA}, c = 9.012 {\AA}, β = 97.13°. The result of X-ray fluorescence gives a Zr(Hf):S mole ratio 1:2.97. The Raman spectrum of the ZrS3 nanocrystallites has a slightly red shift in comparison with that of ZrS 3 single crystals. The room temperature photoluminescence of ZrS 3 nanocrystallites is also reported.",

keywords = "A. Inorganic compounds, B. Chemical synthesis, C. X-ray diffraction",

author = "Liying Huang and Kaibin Tang and Qing Yang and Guozhen Shen and Shaojin Jia",

year = "2004",

month = jun,

day = "8",

doi = "10.1016/j.materresbull.2004.02.019",

language = "English",

volume = "39",

pages = "1083--1089",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd.",

number = "7-8",

}

TY - JOUR

T1 - Synthesis and characterization of ZrS3 nanocrystallites

AU - Huang, Liying

AU - Tang, Kaibin

AU - Yang, Qing

AU - Shen, Guozhen

AU - Jia, Shaojin

PY - 2004/6/8

Y1 - 2004/6/8

N2 - ZrS3 nanocrystallites have been synthesized via a solvothermal route by the reaction between ZrCl4 and thiourea at relatively low temperature. The product was characterized by X-ray diffraction (XRD), transmission electron microscope, X-ray fluorescence, Raman spectrum, and photoluminescence (PL). X-ray diffraction pattern shows the monoclinic cell of ZrS3 with the lattice constants a = 5.128 Å, b = 3.611 Å, c = 9.012 Å, β = 97.13°. The result of X-ray fluorescence gives a Zr(Hf):S mole ratio 1:2.97. The Raman spectrum of the ZrS3 nanocrystallites has a slightly red shift in comparison with that of ZrS 3 single crystals. The room temperature photoluminescence of ZrS 3 nanocrystallites is also reported.

AB - ZrS3 nanocrystallites have been synthesized via a solvothermal route by the reaction between ZrCl4 and thiourea at relatively low temperature. The product was characterized by X-ray diffraction (XRD), transmission electron microscope, X-ray fluorescence, Raman spectrum, and photoluminescence (PL). X-ray diffraction pattern shows the monoclinic cell of ZrS3 with the lattice constants a = 5.128 Å, b = 3.611 Å, c = 9.012 Å, β = 97.13°. The result of X-ray fluorescence gives a Zr(Hf):S mole ratio 1:2.97. The Raman spectrum of the ZrS3 nanocrystallites has a slightly red shift in comparison with that of ZrS 3 single crystals. The room temperature photoluminescence of ZrS 3 nanocrystallites is also reported.

KW - A. Inorganic compounds

KW - B. Chemical synthesis

KW - C. X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=2442678017&partnerID=8YFLogxK

U2 - 10.1016/j.materresbull.2004.02.019

DO - 10.1016/j.materresbull.2004.02.019

M3 - Article

AN - SCOPUS:2442678017

SN - 0025-5408

VL - 39

SP - 1083

EP - 1089

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 7-8

ER -

Synthesis and characterization of ZrS₃ nanocrystallites

Abstract

Keywords

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