@inbook{3456b6beee1d4468b3fdf224cf9ec2e6,
title = "Synthesis and characterization of novel open-framework cobalt phosphates from aqueous-alcoholic systems",
abstract = "Three amine-occluding open-framework cobalt phosphates, CoPO4-n (n=1–3) have been synthesized from aqueous-alcoholic systems of Co(Ac)2-H3PO4-R-EG-H2O, where R stands for an amine and EG for ethylene glycol. It is found that diamines can be exclusively used as the structure-directing templates during the crystallization of open-framework cobalt phosphates. The structures of CoPO4-n were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP) analysis, infrared spectroscopy (IR) and UV-Vis diffuse reflectance spectroscopy (DRS). The as-synthesized compounds are all blue in color and exhibit UV-Vis spectra characteristic of tetrahedrallycoordinated Co atoms. Thermal analysis shows that the templates occluded in CoPO4-n decompose endothermally at 400–450 °C, and after the template decomposition, the materials become X-ray amorphous.",
author = "Jihong Yu and Qiuming Gao and Jiesheng Chen and Ruren Xu",
note = "Publisher Copyright: {\textcopyright} 1997 Elsevier B.V.",
year = "1997",
month = jan,
day = "1",
doi = "10.1016/S0167-2991(97)80579-4",
language = "English",
isbn = "9780444823441",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier Inc.",
pages = "381--388",
editor = "Hakze Chon and Son-Ki Ihm and Uh, {Young Sun}",
booktitle = "Progress in Zeolite and Microporous Materials",
address = "United States",
}