Synthesis and characterization of diazidoglyoxime

Xiao Jun Wang; Qiang Su; Guang Yuan Zhang; Xia Wang; Jun Feng Wang

doi:10.11943/j.issn.1006-9941.2014.06.005

Synthesis and characterization of diazidoglyoxime

Xiao Jun Wang, Qiang Su, Guang Yuan Zhang, Xia Wang, Jun Feng Wang

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H₂O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H₅₀ is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.

Original language	English
Pages (from-to)	741-743
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	22
Issue number	6
DOIs	https://doi.org/10.11943/j.issn.1006-9941.2014.06.005
Publication status	Published - 25 Dec 2014

Keywords

Diazidoglyoxime
Energetic materials
Organic chemistry
Synthesis

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10.11943/j.issn.1006-9941.2014.06.005

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title = "Synthesis and characterization of diazidoglyoxime",

abstract = "Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H50 is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.",

keywords = "Diazidoglyoxime, Energetic materials, Organic chemistry, Synthesis",

author = "Wang, {Xiao Jun} and Qiang Su and Zhang, {Guang Yuan} and Xia Wang and Wang, {Jun Feng}",

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doi = "10.11943/j.issn.1006-9941.2014.06.005",

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TY - JOUR

T1 - Synthesis and characterization of diazidoglyoxime

AU - Wang, Xiao Jun

AU - Su, Qiang

AU - Zhang, Guang Yuan

AU - Wang, Xia

AU - Wang, Jun Feng

PY - 2014/12/25

Y1 - 2014/12/25

N2 - Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H50 is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.

AB - Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H50 is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.

KW - Diazidoglyoxime

KW - Energetic materials

KW - Organic chemistry

KW - Synthesis

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U2 - 10.11943/j.issn.1006-9941.2014.06.005

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AN - SCOPUS:84922249199

SN - 1006-9941

VL - 22

SP - 741

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JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

Synthesis and characterization of diazidoglyoxime

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