Synthesis and characterization of a new three-dimensional aluminophosphate [Al11P12O48][C4H12N 2][C4H11N2] with an Al/P ratio of 11: 12

K. Wang; J. Yu; Z. Shi; P. Miao; W. Yan; R. Xu

doi:10.1039/b102327f

Synthesis and characterization of a new three-dimensional aluminophosphate [Al₁₁P₁₂O₄₈][C₄H₁₂N ₂][C₄H₁₁N₂] with an Al/P ratio of 11: 12

K. Wang, J. Yu, Z. Shi, P. Miao, W. Yan, R. Xu^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Employing piperazine as a template, a new three-dimensional aluminophosphate [Al₁₁P₁₂O₄₈][C₄H₁₂N ₂] (denoted AlPO-CJ11) has been prepared hydrothermally. The as-synthesized product has been characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric and differential thermal analyses. Single crystal X-ray diffraction analysis shows that AlPO-CJ11 crystallizes in the trigonal space group R3̄c (no. 167) with a = 14.045(2) Å, c = 42.091(6) Å, V = 7191.0(16) Å³, and Z = 6. The framework structure of AlPO-CJ11 is constructed from two new types of chiral cage and has a new stoichiometry with an Al/P ratio of 11 : 12. The possible locations of the templates in the cages have been investigated by molecular modeling.

Original language	English
Pages (from-to)	1809-1812
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/b102327f
Publication status	Published - 2001
Externally published	Yes

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@article{7565ae49f58c4501be55592eb894fca4,

title = "Synthesis and characterization of a new three-dimensional aluminophosphate [Al11P12O48][C4H12N 2][C4H11N2] with an Al/P ratio of 11: 12",

abstract = "Employing piperazine as a template, a new three-dimensional aluminophosphate [Al11P12O48][C4H12N 2] (denoted AlPO-CJ11) has been prepared hydrothermally. The as-synthesized product has been characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric and differential thermal analyses. Single crystal X-ray diffraction analysis shows that AlPO-CJ11 crystallizes in the trigonal space group R{\=3}c (no. 167) with a = 14.045(2) {\AA}, c = 42.091(6) {\AA}, V = 7191.0(16) {\AA}3, and Z = 6. The framework structure of AlPO-CJ11 is constructed from two new types of chiral cage and has a new stoichiometry with an Al/P ratio of 11 : 12. The possible locations of the templates in the cages have been investigated by molecular modeling.",

author = "K. Wang and J. Yu and Z. Shi and P. Miao and W. Yan and R. Xu",

year = "2001",

doi = "10.1039/b102327f",

language = "English",

pages = "1809--1812",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Synthesis and characterization of a new three-dimensional aluminophosphate [Al11P12O48][C4H12N 2][C4H11N2] with an Al/P ratio of 11

T2 - 12

AU - Wang, K.

AU - Yu, J.

AU - Shi, Z.

AU - Miao, P.

AU - Yan, W.

AU - Xu, R.

PY - 2001

Y1 - 2001

N2 - Employing piperazine as a template, a new three-dimensional aluminophosphate [Al11P12O48][C4H12N 2] (denoted AlPO-CJ11) has been prepared hydrothermally. The as-synthesized product has been characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric and differential thermal analyses. Single crystal X-ray diffraction analysis shows that AlPO-CJ11 crystallizes in the trigonal space group R3̄c (no. 167) with a = 14.045(2) Å, c = 42.091(6) Å, V = 7191.0(16) Å3, and Z = 6. The framework structure of AlPO-CJ11 is constructed from two new types of chiral cage and has a new stoichiometry with an Al/P ratio of 11 : 12. The possible locations of the templates in the cages have been investigated by molecular modeling.

AB - Employing piperazine as a template, a new three-dimensional aluminophosphate [Al11P12O48][C4H12N 2] (denoted AlPO-CJ11) has been prepared hydrothermally. The as-synthesized product has been characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric and differential thermal analyses. Single crystal X-ray diffraction analysis shows that AlPO-CJ11 crystallizes in the trigonal space group R3̄c (no. 167) with a = 14.045(2) Å, c = 42.091(6) Å, V = 7191.0(16) Å3, and Z = 6. The framework structure of AlPO-CJ11 is constructed from two new types of chiral cage and has a new stoichiometry with an Al/P ratio of 11 : 12. The possible locations of the templates in the cages have been investigated by molecular modeling.

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U2 - 10.1039/b102327f

DO - 10.1039/b102327f

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SN - 1470-479X

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JO - Journal of the Chemical Society. Dalton Transactions

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ER -

Synthesis and characterization of a new three-dimensional aluminophosphate [Al₁₁P₁₂O₄₈][C₄H₁₂N ₂][C₄H₁₁N₂] with an Al/P ratio of 11: 12

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