Synthesis and characterization of a new fluoroaluminophosphate chain

Wenfu Yan; Jihong Yu; Zhan Shi; Yu Wang; Yongcun Zou; Ruren Xu

doi:10.1006/jssc.2001.9307

Synthesis and characterization of a new fluoroaluminophosphate chain

Wenfu Yan, Jihong Yu, Zhan Shi, Yu Wang, Yongcun Zou, Ruren Xu^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A new fluoroaluminophosphate chain, denoted AlPO-CJ10, has been synthesized in the system Al(PrOⁱ)₃-H₃PO₄ hexamethyleneimine-HF-TEG and its structure solved by singlecrystal X-ray diffraction analysis. It is characterized by X-ray powder diffraction (XRD), ion-selective electrodes (ISE), inductively coupled plasma (ICP), thermogravimetric (TG), and elemental analyses. The compound has an empirical formula of [AlP₂O₅(OH)₃F]·[C₆H ₁₂NH₂] and crystallizes in the orthorhombic space group Pnma (No. 62) with a = 25.547(10) Å, b = 6.915(2) Å, c = 7.179(2) Å, Z = 4, R₁ = 0.0550, and wR₂ = 0.1382. Its structure is built up by alternation of tetrahedral PO₃(OH) and PO₂(OH)₂ units and octahedral AlO₄F₂ units to form one-dimensional AlP₂O₈H₃F^- macroanionic chains containing an infinite -Al-F-Al- linkage. The inorganic chains are held together by protonated hexamethyleneimine through H bonds.

Original language	English
Pages (from-to)	259-265
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	161
Issue number	2
DOIs	https://doi.org/10.1006/jssc.2001.9307
Publication status	Published - 1 Nov 2001
Externally published	Yes

Keywords

Chain
Fluoroaluminophosphate
Solvothermal
Synthesis

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10.1006/jssc.2001.9307

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title = "Synthesis and characterization of a new fluoroaluminophosphate chain",

abstract = "A new fluoroaluminophosphate chain, denoted AlPO-CJ10, has been synthesized in the system Al(PrOi)3-H3PO4 hexamethyleneimine-HF-TEG and its structure solved by singlecrystal X-ray diffraction analysis. It is characterized by X-ray powder diffraction (XRD), ion-selective electrodes (ISE), inductively coupled plasma (ICP), thermogravimetric (TG), and elemental analyses. The compound has an empirical formula of [AlP2O5(OH)3F]·[C6H 12NH2] and crystallizes in the orthorhombic space group Pnma (No. 62) with a = 25.547(10) {\AA}, b = 6.915(2) {\AA}, c = 7.179(2) {\AA}, Z = 4, R1 = 0.0550, and wR2 = 0.1382. Its structure is built up by alternation of tetrahedral PO3(OH) and PO2(OH)2 units and octahedral AlO4F2 units to form one-dimensional AlP2O8H3F- macroanionic chains containing an infinite -Al-F-Al- linkage. The inorganic chains are held together by protonated hexamethyleneimine through H bonds.",

keywords = "Chain, Fluoroaluminophosphate, Solvothermal, Synthesis",

author = "Wenfu Yan and Jihong Yu and Zhan Shi and Yu Wang and Yongcun Zou and Ruren Xu",

year = "2001",

month = nov,

day = "1",

doi = "10.1006/jssc.2001.9307",

language = "English",

volume = "161",

pages = "259--265",

journal = "Journal of Solid State Chemistry",

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TY - JOUR

T1 - Synthesis and characterization of a new fluoroaluminophosphate chain

AU - Yan, Wenfu

AU - Yu, Jihong

AU - Shi, Zhan

AU - Wang, Yu

AU - Zou, Yongcun

AU - Xu, Ruren

PY - 2001/11/1

Y1 - 2001/11/1

N2 - A new fluoroaluminophosphate chain, denoted AlPO-CJ10, has been synthesized in the system Al(PrOi)3-H3PO4 hexamethyleneimine-HF-TEG and its structure solved by singlecrystal X-ray diffraction analysis. It is characterized by X-ray powder diffraction (XRD), ion-selective electrodes (ISE), inductively coupled plasma (ICP), thermogravimetric (TG), and elemental analyses. The compound has an empirical formula of [AlP2O5(OH)3F]·[C6H 12NH2] and crystallizes in the orthorhombic space group Pnma (No. 62) with a = 25.547(10) Å, b = 6.915(2) Å, c = 7.179(2) Å, Z = 4, R1 = 0.0550, and wR2 = 0.1382. Its structure is built up by alternation of tetrahedral PO3(OH) and PO2(OH)2 units and octahedral AlO4F2 units to form one-dimensional AlP2O8H3F- macroanionic chains containing an infinite -Al-F-Al- linkage. The inorganic chains are held together by protonated hexamethyleneimine through H bonds.

AB - A new fluoroaluminophosphate chain, denoted AlPO-CJ10, has been synthesized in the system Al(PrOi)3-H3PO4 hexamethyleneimine-HF-TEG and its structure solved by singlecrystal X-ray diffraction analysis. It is characterized by X-ray powder diffraction (XRD), ion-selective electrodes (ISE), inductively coupled plasma (ICP), thermogravimetric (TG), and elemental analyses. The compound has an empirical formula of [AlP2O5(OH)3F]·[C6H 12NH2] and crystallizes in the orthorhombic space group Pnma (No. 62) with a = 25.547(10) Å, b = 6.915(2) Å, c = 7.179(2) Å, Z = 4, R1 = 0.0550, and wR2 = 0.1382. Its structure is built up by alternation of tetrahedral PO3(OH) and PO2(OH)2 units and octahedral AlO4F2 units to form one-dimensional AlP2O8H3F- macroanionic chains containing an infinite -Al-F-Al- linkage. The inorganic chains are held together by protonated hexamethyleneimine through H bonds.

KW - Chain

KW - Fluoroaluminophosphate

KW - Solvothermal

KW - Synthesis

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DO - 10.1006/jssc.2001.9307

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Synthesis and characterization of a new fluoroaluminophosphate chain

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