Synthesis and characteristics of novel, high-nitrogen 1,2,4-oxadiazoles

Zhanda Fu; Yang Wang; Li Yang; Rui Su; Jun Chen; Fude Nie; Jinglun Huang; Fu Xue Chen

doi:10.1039/c4ra00255e

Synthesis and characteristics of novel, high-nitrogen 1,2,4-oxadiazoles

Zhanda Fu, Yang Wang, Li Yang, Rui Su, Jun Chen, Fude Nie, Jinglun Huang, Fu Xue Chen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Two novel high-nitrogen energetic compounds 3-azido-5-guanidino-1,2,4- oxadiazole (AOG, N% 66.65) and 3,6-bis(3′-azido-1′,2′, 4′-oxadiazole-5′-guanyl)-1,2,4,5-tetrazine (AOG₂Tz, N% 67.62) were synthesized and fully characterized. The thermal stability of them was evaluated with differential scanning calorimetry (DSC). AOG and AOG ₂Tz decomposed at 196 °C and 210 °C, respectively. They exhibit high density, favourable detonation properties, and they have low sensitivity to impact.

Original language	English
Pages (from-to)	11859-11861
Number of pages	3
Journal	RSC Advances
Volume	4
Issue number	23
DOIs	https://doi.org/10.1039/c4ra00255e
Publication status	Published - 2014

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Fu, Z., Wang, Y., Yang, L., Su, R., Chen, J., Nie, F., Huang, J., & Chen, F. X. (2014). Synthesis and characteristics of novel, high-nitrogen 1,2,4-oxadiazoles. RSC Advances, 4(23), 11859-11861. https://doi.org/10.1039/c4ra00255e

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title = "Synthesis and characteristics of novel, high-nitrogen 1,2,4-oxadiazoles",

abstract = "Two novel high-nitrogen energetic compounds 3-azido-5-guanidino-1,2,4- oxadiazole (AOG, N% 66.65) and 3,6-bis(3′-azido-1′,2′, 4′-oxadiazole-5′-guanyl)-1,2,4,5-tetrazine (AOG2Tz, N% 67.62) were synthesized and fully characterized. The thermal stability of them was evaluated with differential scanning calorimetry (DSC). AOG and AOG 2Tz decomposed at 196 °C and 210 °C, respectively. They exhibit high density, favourable detonation properties, and they have low sensitivity to impact.",

author = "Zhanda Fu and Yang Wang and Li Yang and Rui Su and Jun Chen and Fude Nie and Jinglun Huang and Chen, {Fu Xue}",

year = "2014",

doi = "10.1039/c4ra00255e",

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volume = "4",

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AU - Fu, Zhanda

AU - Wang, Yang

AU - Yang, Li

AU - Su, Rui

AU - Chen, Jun

AU - Nie, Fude

AU - Huang, Jinglun

AU - Chen, Fu Xue

PY - 2014

Y1 - 2014

N2 - Two novel high-nitrogen energetic compounds 3-azido-5-guanidino-1,2,4- oxadiazole (AOG, N% 66.65) and 3,6-bis(3′-azido-1′,2′, 4′-oxadiazole-5′-guanyl)-1,2,4,5-tetrazine (AOG2Tz, N% 67.62) were synthesized and fully characterized. The thermal stability of them was evaluated with differential scanning calorimetry (DSC). AOG and AOG 2Tz decomposed at 196 °C and 210 °C, respectively. They exhibit high density, favourable detonation properties, and they have low sensitivity to impact.

AB - Two novel high-nitrogen energetic compounds 3-azido-5-guanidino-1,2,4- oxadiazole (AOG, N% 66.65) and 3,6-bis(3′-azido-1′,2′, 4′-oxadiazole-5′-guanyl)-1,2,4,5-tetrazine (AOG2Tz, N% 67.62) were synthesized and fully characterized. The thermal stability of them was evaluated with differential scanning calorimetry (DSC). AOG and AOG 2Tz decomposed at 196 °C and 210 °C, respectively. They exhibit high density, favourable detonation properties, and they have low sensitivity to impact.

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DO - 10.1039/c4ra00255e

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EP - 11861

JO - RSC Advances

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Synthesis and characteristics of novel, high-nitrogen 1,2,4-oxadiazoles

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