Syntheses and crystal structures of two novel zinc(II) coordination polymers

Jun Tao; Xin Yin; Yun Bao Jiang; Le Fu Yang; Rong Bin Huang; Lan Sun Zheng

doi:10.1002/ejic.200300021

Syntheses and crystal structures of two novel zinc(II) coordination polymers

Jun Tao^*, Xin Yin, Yun Bao Jiang, Le Fu Yang, Rong Bin Huang, Lan Sun Zheng

^*Corresponding author for this work

Xiamen University

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Two novel zinc(II) coordination polymers, [Zn₃(μ3-OH)₂(nip)₂] (1) and [Zn₂(nip)₂(4,4′-bpy)₃· (OH₂)] (2) (H₂nip = 5-nitroisophthalic acid, 4,4′-bpy = 4,4′-bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5-nitroisophthalate (nip) (for 1) and zinc nitrate, 5-nitroisophthalate and 4,4′-bipyridyl (for 2). Complex 1 displays a two-dimensional structure that is built from [Zn₃(μ₃-OH)₂]_n chains, while com-plex 2 is a three-dimensional structure formed by the interpenetration of two-dimensional hydrogen-bonded bilayers. The photoluminescent properties of complex 1 have also been investigated.

Original language	English
Pages (from-to)	2678-2682
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	14
DOIs	https://doi.org/10.1002/ejic.200300021
Publication status	Published - 25 Jul 2003
Externally published	Yes

Keywords

Coordination polymers
Hydrogen bonds
N ligands
Photoluminescence
Zinc

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10.1002/ejic.200300021

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@article{a2456e374d54460c94c85f9ebb501abf,

title = "Syntheses and crystal structures of two novel zinc(II) coordination polymers",

abstract = "Two novel zinc(II) coordination polymers, [Zn3(μ3-OH)2(nip)2] (1) and [Zn2(nip)2(4,4′-bpy)3· (OH2)] (2) (H2nip = 5-nitroisophthalic acid, 4,4′-bpy = 4,4′-bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5-nitroisophthalate (nip) (for 1) and zinc nitrate, 5-nitroisophthalate and 4,4′-bipyridyl (for 2). Complex 1 displays a two-dimensional structure that is built from [Zn3(μ3-OH)2]n chains, while com-plex 2 is a three-dimensional structure formed by the interpenetration of two-dimensional hydrogen-bonded bilayers. The photoluminescent properties of complex 1 have also been investigated.",

keywords = "Coordination polymers, Hydrogen bonds, N ligands, Photoluminescence, Zinc",

author = "Jun Tao and Xin Yin and Jiang, {Yun Bao} and Yang, {Le Fu} and Huang, {Rong Bin} and Zheng, {Lan Sun}",

year = "2003",

month = jul,

day = "25",

doi = "10.1002/ejic.200300021",

language = "English",

pages = "2678--2682",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "14",

}

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T1 - Syntheses and crystal structures of two novel zinc(II) coordination polymers

AU - Tao, Jun

AU - Yin, Xin

AU - Jiang, Yun Bao

AU - Yang, Le Fu

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2003/7/25

Y1 - 2003/7/25

N2 - Two novel zinc(II) coordination polymers, [Zn3(μ3-OH)2(nip)2] (1) and [Zn2(nip)2(4,4′-bpy)3· (OH2)] (2) (H2nip = 5-nitroisophthalic acid, 4,4′-bpy = 4,4′-bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5-nitroisophthalate (nip) (for 1) and zinc nitrate, 5-nitroisophthalate and 4,4′-bipyridyl (for 2). Complex 1 displays a two-dimensional structure that is built from [Zn3(μ3-OH)2]n chains, while com-plex 2 is a three-dimensional structure formed by the interpenetration of two-dimensional hydrogen-bonded bilayers. The photoluminescent properties of complex 1 have also been investigated.

AB - Two novel zinc(II) coordination polymers, [Zn3(μ3-OH)2(nip)2] (1) and [Zn2(nip)2(4,4′-bpy)3· (OH2)] (2) (H2nip = 5-nitroisophthalic acid, 4,4′-bpy = 4,4′-bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5-nitroisophthalate (nip) (for 1) and zinc nitrate, 5-nitroisophthalate and 4,4′-bipyridyl (for 2). Complex 1 displays a two-dimensional structure that is built from [Zn3(μ3-OH)2]n chains, while com-plex 2 is a three-dimensional structure formed by the interpenetration of two-dimensional hydrogen-bonded bilayers. The photoluminescent properties of complex 1 have also been investigated.

KW - Coordination polymers

KW - Hydrogen bonds

KW - N ligands

KW - Photoluminescence

KW - Zinc

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U2 - 10.1002/ejic.200300021

DO - 10.1002/ejic.200300021

M3 - Article

AN - SCOPUS:0042658186

SN - 1434-1948

SP - 2678

EP - 2682

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 14

ER -

Syntheses and crystal structures of two novel zinc(II) coordination polymers

Abstract

Keywords

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