Study on synthesis of N-propargyl-R-2-heptylamine

Lin Yang; Yu Lin Deng; Rong Ji Dai; Wei Liu

Study on synthesis of N-propargyl-R-2-heptylamine

Lin Yang^*, Yu Lin Deng, Rong Ji Dai, Wei Liu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.

Original language	English
Pages (from-to)	44-46+48
Journal	Xiandai Huagong/Modern Chemical Industry
Volume	28
Issue number	10
Publication status	Published - Oct 2008

Keywords

N-propargyl-R-2-heptylamine
R-2-heptylamine
Resolution
Synthesis

Cite this

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title = "Study on synthesis of N-propargyl-R-2-heptylamine",

abstract = "A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.",

keywords = "N-propargyl-R-2-heptylamine, R-2-heptylamine, Resolution, Synthesis",

author = "Lin Yang and Deng, {Yu Lin} and Dai, {Rong Ji} and Wei Liu",

year = "2008",

month = oct,

language = "English",

volume = "28",

pages = "44--46+48",

journal = "Xiandai Huagong/Modern Chemical Industry",

issn = "0253-4320",

publisher = "China National Chemical Information Center",

number = "10",

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TY - JOUR

T1 - Study on synthesis of N-propargyl-R-2-heptylamine

AU - Yang, Lin

AU - Deng, Yu Lin

AU - Dai, Rong Ji

AU - Liu, Wei

PY - 2008/10

Y1 - 2008/10

N2 - A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.

AB - A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.

KW - N-propargyl-R-2-heptylamine

KW - R-2-heptylamine

KW - Resolution

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=55949099646&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:55949099646

SN - 0253-4320

VL - 28

SP - 44-46+48

JO - Xiandai Huagong/Modern Chemical Industry

JF - Xiandai Huagong/Modern Chemical Industry

IS - 10

ER -

Study on synthesis of N-propargyl-R-2-heptylamine

Abstract

Keywords

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