Study of crystal defects and spectroscopy characteristics of ammonium polyphosphate

De Qi Yi*, Rong Jie Yang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

Two kinds of commercial ammonium polyphosphate (APP) and three kinds of APP which were prepared in the laboratory were studied by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In identification of the form II crystal APP by XRD and FTIR, some discrepancies were discussed. It is pointed out that the absorbance of the FTIR spectra at 682 cm-1 can exist not only in the form I APP, but also in the form II APP with the crystal lattice defects. The SEM images indicate that the form II APP is of multilayer crystal structure. XRD and TEM can reveal the crystal lattice defects. Copyright Protection.

Original languageEnglish
Pages (from-to)238-242
Number of pages5
JournalJournal of Beijing Institute of Technology (English Edition)
Volume18
Issue number2
Publication statusPublished - Jun 2009

Keywords

  • Ammonium polyphosphate (APP)
  • Crystal defects
  • Infrared spectroscopy
  • X-ray diffraction

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