Structures and templating effect in the formation of 2D layered aluminophosphates with Al3P4O163- stoichiometry

Jiyang Li; Jihong Yu; Wenfu Yan; Yihua Xu; Wenguo Xu; Shilun Qiu; Ruren Xu

doi:10.1021/cm990289n

Structures and templating effect in the formation of 2D layered aluminophosphates with Al₃P₄O₁₆^3- stoichiometry

Jiyang Li^*, Jihong Yu, Wenfu Yan, Yihua Xu, Wenguo Xu, Shilun Qiu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

The structural features of a family of layered aluminophosphates with Al₃P₄O₁₆ ^3- stoichiometry (denoted L-n) have been discussed. Their 2D sheets are stabilized by protonated organic amines through H-bonding interactions with certain regularity. The templating ability of various organic amines for the experimental inorganic layers is investigated in terms of the energies of the host-template interactions. Some experimental phenomena, such as the packing sequence of the inorganic layers and the co-templating role of two types of templates on the formation of some structures, can be explained by energy calculation results. Some organic templates that can potentially direct the formation of a given host can be predicted. This further assists in the rational synthesis of 2D layered compounds with specific structures.

Original language	English
Pages (from-to)	2600-2606
Number of pages	7
Journal	Chemistry of Materials
Volume	11
Issue number	9
DOIs	https://doi.org/10.1021/cm990289n
Publication status	Published - 1999
Externally published	Yes

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Li, J., Yu, J., Yan, W., Xu, Y., Xu, W., Qiu, S., & Xu, R. (1999). Structures and templating effect in the formation of 2D layered aluminophosphates with Al₃P₄O₁₆^3- stoichiometry. Chemistry of Materials, 11(9), 2600-2606. https://doi.org/10.1021/cm990289n

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abstract = "The structural features of a family of layered aluminophosphates with Al3P4O16 3- stoichiometry (denoted L-n) have been discussed. Their 2D sheets are stabilized by protonated organic amines through H-bonding interactions with certain regularity. The templating ability of various organic amines for the experimental inorganic layers is investigated in terms of the energies of the host-template interactions. Some experimental phenomena, such as the packing sequence of the inorganic layers and the co-templating role of two types of templates on the formation of some structures, can be explained by energy calculation results. Some organic templates that can potentially direct the formation of a given host can be predicted. This further assists in the rational synthesis of 2D layered compounds with specific structures.",

author = "Jiyang Li and Jihong Yu and Wenfu Yan and Yihua Xu and Wenguo Xu and Shilun Qiu and Ruren Xu",

year = "1999",

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T1 - Structures and templating effect in the formation of 2D layered aluminophosphates with Al3P4O163- stoichiometry

AU - Li, Jiyang

AU - Yu, Jihong

AU - Yan, Wenfu

AU - Xu, Yihua

AU - Xu, Wenguo

AU - Qiu, Shilun

AU - Xu, Ruren

PY - 1999

Y1 - 1999

N2 - The structural features of a family of layered aluminophosphates with Al3P4O16 3- stoichiometry (denoted L-n) have been discussed. Their 2D sheets are stabilized by protonated organic amines through H-bonding interactions with certain regularity. The templating ability of various organic amines for the experimental inorganic layers is investigated in terms of the energies of the host-template interactions. Some experimental phenomena, such as the packing sequence of the inorganic layers and the co-templating role of two types of templates on the formation of some structures, can be explained by energy calculation results. Some organic templates that can potentially direct the formation of a given host can be predicted. This further assists in the rational synthesis of 2D layered compounds with specific structures.

AB - The structural features of a family of layered aluminophosphates with Al3P4O16 3- stoichiometry (denoted L-n) have been discussed. Their 2D sheets are stabilized by protonated organic amines through H-bonding interactions with certain regularity. The templating ability of various organic amines for the experimental inorganic layers is investigated in terms of the energies of the host-template interactions. Some experimental phenomena, such as the packing sequence of the inorganic layers and the co-templating role of two types of templates on the formation of some structures, can be explained by energy calculation results. Some organic templates that can potentially direct the formation of a given host can be predicted. This further assists in the rational synthesis of 2D layered compounds with specific structures.

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Structures and templating effect in the formation of 2D layered aluminophosphates with Al₃P₄O₁₆^3- stoichiometry

Abstract

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