Structural diversity of a family of aluminophosphates with Al/P ratio of non-unity

Jihong Yu; Ruren Xu; Jiyang Li

doi:10.1016/S1293-2558(00)00120-5

Structural diversity of a family of aluminophosphates with Al/P ratio of non-unity

Jihong Yu, Ruren Xu^*, Jiyang Li

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A family of organically templated aluminophosphates (denoted AlPOs) with an Al/P ratio of non-unity has been prepared with 1-D chain, 2-D layer and 3-D open-framework architectures. Their inorganic parts are constructed from alternating Al-centered polyhedra (AlO₄, AlO₅, AlO₄(OH₂)₂) and P-centered tetrahedra P(O-Al)(n)O_4-(n) (n = 0, 1, 2, 3). The existence of terminal P-OH and/or P=O groups in the structures results in the deviation of Al/P ratio from unity, and the commonly encountered Al/P ratios are 1/2, 3/5, 2/3, 3/4, 4/5 and 5/6. This review will discuss the structural features of these AlPOs with various dimensionalities and stoichiometries. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

Original language	English
Pages (from-to)	181-192
Number of pages	12
Journal	Solid State Sciences
Volume	2
Issue number	2
DOIs	https://doi.org/10.1016/S1293-2558(00)00120-5
Publication status	Published - 2000
Externally published	Yes

Keywords

Al/P ratio
Aluminophosphates
Dimensionality
Stoichiometry
Structure

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10.1016/S1293-2558(00)00120-5

Cite this

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abstract = "A family of organically templated aluminophosphates (denoted AlPOs) with an Al/P ratio of non-unity has been prepared with 1-D chain, 2-D layer and 3-D open-framework architectures. Their inorganic parts are constructed from alternating Al-centered polyhedra (AlO4, AlO5, AlO4(OH2)2) and P-centered tetrahedra P(O-Al)(n)O4-(n) (n = 0, 1, 2, 3). The existence of terminal P-OH and/or P=O groups in the structures results in the deviation of Al/P ratio from unity, and the commonly encountered Al/P ratios are 1/2, 3/5, 2/3, 3/4, 4/5 and 5/6. This review will discuss the structural features of these AlPOs with various dimensionalities and stoichiometries. (C) 2000 Editions scientifiques et medicales Elsevier SAS.",

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AU - Yu, Jihong

AU - Xu, Ruren

AU - Li, Jiyang

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N2 - A family of organically templated aluminophosphates (denoted AlPOs) with an Al/P ratio of non-unity has been prepared with 1-D chain, 2-D layer and 3-D open-framework architectures. Their inorganic parts are constructed from alternating Al-centered polyhedra (AlO4, AlO5, AlO4(OH2)2) and P-centered tetrahedra P(O-Al)(n)O4-(n) (n = 0, 1, 2, 3). The existence of terminal P-OH and/or P=O groups in the structures results in the deviation of Al/P ratio from unity, and the commonly encountered Al/P ratios are 1/2, 3/5, 2/3, 3/4, 4/5 and 5/6. This review will discuss the structural features of these AlPOs with various dimensionalities and stoichiometries. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

AB - A family of organically templated aluminophosphates (denoted AlPOs) with an Al/P ratio of non-unity has been prepared with 1-D chain, 2-D layer and 3-D open-framework architectures. Their inorganic parts are constructed from alternating Al-centered polyhedra (AlO4, AlO5, AlO4(OH2)2) and P-centered tetrahedra P(O-Al)(n)O4-(n) (n = 0, 1, 2, 3). The existence of terminal P-OH and/or P=O groups in the structures results in the deviation of Al/P ratio from unity, and the commonly encountered Al/P ratios are 1/2, 3/5, 2/3, 3/4, 4/5 and 5/6. This review will discuss the structural features of these AlPOs with various dimensionalities and stoichiometries. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

KW - Al/P ratio

KW - Aluminophosphates

KW - Dimensionality

KW - Stoichiometry

KW - Structure

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Structural diversity of a family of aluminophosphates with Al/P ratio of non-unity

Abstract

Keywords

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