Structural adjustment of bipyridinium-bearing Cu(II) coordination polymers and the adsorption properties toward methanol, water and ethanol vapors

Qi Qi Zhang; Xiao Dong Yang; Li Sun; Rui Yun Guo; Ming Chen; Jie Zhang

doi:10.1016/j.inoche.2017.11.011

Structural adjustment of bipyridinium-bearing Cu(II) coordination polymers and the adsorption properties toward methanol, water and ethanol vapors

Qi Qi Zhang, Xiao Dong Yang, Li Sun, Rui Yun Guo, Ming Chen, Jie Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Two bipyridinium-bearing Cu(II) coordination polymers, [Cu(BCbpy)(ox)(H₂O)]·H₂O (1) and [Cu₂(BCbpy)₂(ox)₂]·3H₂O·DMF (2), have been synthesized and structurally characterized. Upon solvent modulation, the structure transformation from a closely-packed 1D chain to a 2D laminar network with parallelogram-shaped channels can be achieved. More interestingly, the charge separated skeleton of BCbpy ligand incorporated in compound 2 makes the pore space polarized, endowing it with different adsorption abilities for methanol, water and ethanol vapors.

Original language	English
Pages (from-to)	27-29
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	87
DOIs	https://doi.org/10.1016/j.inoche.2017.11.011
Publication status	Published - Jan 2018

Keywords

Bipyridinium
Coordination polymers
Vapor adsorption

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10.1016/j.inoche.2017.11.011

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@article{411519afc84a4a07af757a5a547adf4d,

title = "Structural adjustment of bipyridinium-bearing Cu(II) coordination polymers and the adsorption properties toward methanol, water and ethanol vapors",

abstract = "Two bipyridinium-bearing Cu(II) coordination polymers, [Cu(BCbpy)(ox)(H2O)]·H2O (1) and [Cu2(BCbpy)2(ox)2]·3H2O·DMF (2), have been synthesized and structurally characterized. Upon solvent modulation, the structure transformation from a closely-packed 1D chain to a 2D laminar network with parallelogram-shaped channels can be achieved. More interestingly, the charge separated skeleton of BCbpy ligand incorporated in compound 2 makes the pore space polarized, endowing it with different adsorption abilities for methanol, water and ethanol vapors.",

keywords = "Bipyridinium, Coordination polymers, Vapor adsorption",

author = "Zhang, {Qi Qi} and Yang, {Xiao Dong} and Li Sun and Guo, {Rui Yun} and Ming Chen and Jie Zhang",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2018",

month = jan,

doi = "10.1016/j.inoche.2017.11.011",

language = "English",

volume = "87",

pages = "27--29",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Structural adjustment of bipyridinium-bearing Cu(II) coordination polymers and the adsorption properties toward methanol, water and ethanol vapors

AU - Zhang, Qi Qi

AU - Yang, Xiao Dong

AU - Sun, Li

AU - Guo, Rui Yun

AU - Chen, Ming

AU - Zhang, Jie

PY - 2018/1

Y1 - 2018/1

N2 - Two bipyridinium-bearing Cu(II) coordination polymers, [Cu(BCbpy)(ox)(H2O)]·H2O (1) and [Cu2(BCbpy)2(ox)2]·3H2O·DMF (2), have been synthesized and structurally characterized. Upon solvent modulation, the structure transformation from a closely-packed 1D chain to a 2D laminar network with parallelogram-shaped channels can be achieved. More interestingly, the charge separated skeleton of BCbpy ligand incorporated in compound 2 makes the pore space polarized, endowing it with different adsorption abilities for methanol, water and ethanol vapors.

AB - Two bipyridinium-bearing Cu(II) coordination polymers, [Cu(BCbpy)(ox)(H2O)]·H2O (1) and [Cu2(BCbpy)2(ox)2]·3H2O·DMF (2), have been synthesized and structurally characterized. Upon solvent modulation, the structure transformation from a closely-packed 1D chain to a 2D laminar network with parallelogram-shaped channels can be achieved. More interestingly, the charge separated skeleton of BCbpy ligand incorporated in compound 2 makes the pore space polarized, endowing it with different adsorption abilities for methanol, water and ethanol vapors.

KW - Bipyridinium

KW - Coordination polymers

KW - Vapor adsorption

UR - http://www.scopus.com/inward/record.url?scp=85036498709&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2017.11.011

DO - 10.1016/j.inoche.2017.11.011

M3 - Article

AN - SCOPUS:85036498709

SN - 1387-7003

VL - 87

SP - 27

EP - 29

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Structural adjustment of bipyridinium-bearing Cu(II) coordination polymers and the adsorption properties toward methanol, water and ethanol vapors

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Keywords

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