TY - JOUR
T1 - Stable Interface between a NaCl-AlCl3 Melt and a Liquid Ga Negative Electrode for a Long-Life Stationary Al-Ion Energy Storage Battery
AU - Wang, Junxiang
AU - Jiao, Handong
AU - Song, Wei Li
AU - Wang, Mingyong
AU - Tu, Jiguo
AU - Tang, Zhongfeng
AU - Zhu, Hongmin
N1 - Publisher Copyright:
Copyright © 2020 American Chemical Society.
PY - 2020/4/1
Y1 - 2020/4/1
N2 - Intermediate temperature NaCl-AlCl3-based Al-ion batteries are considered as a promising stationary energy storage system due to their low cost, high safety, etc. However, such a cheap electrolyte has a critical feature, i.e., strong corrosion, which results in the short cycle life of the conventional Al-metal anode and also limits the development of the NaCl-AlCl3-based Al-ion batteries. A noncorrosive electrolyte may be a good choice for addressing the above challenge, while it is difficult to obtain the electrolyte that has advantages of both noncorrosion and low cost. Therefore, here, we report a Ga-metal anode in the affordable NaCl-AlCl3 electrolyte for constructing a long-life stationary Al-ion energy storage system. This featured liquid metal anode shows good alloying and dealloying processes between metallic Ga and Al, as well as renders superior stability of the interface between the electrolyte and the anode (e.g., smoothly running for over 580 h at 2 mA cm-2). No-corrosion and no-pulverization problems appear in this novel liquid/liquid interface. Those advantages demonstrate that the liquid Ga-metal anode has a great promise for the improvement of the NaCl-AlCl3-based Al-ion batteries for large-scale stationary energy storage applications.
AB - Intermediate temperature NaCl-AlCl3-based Al-ion batteries are considered as a promising stationary energy storage system due to their low cost, high safety, etc. However, such a cheap electrolyte has a critical feature, i.e., strong corrosion, which results in the short cycle life of the conventional Al-metal anode and also limits the development of the NaCl-AlCl3-based Al-ion batteries. A noncorrosive electrolyte may be a good choice for addressing the above challenge, while it is difficult to obtain the electrolyte that has advantages of both noncorrosion and low cost. Therefore, here, we report a Ga-metal anode in the affordable NaCl-AlCl3 electrolyte for constructing a long-life stationary Al-ion energy storage system. This featured liquid metal anode shows good alloying and dealloying processes between metallic Ga and Al, as well as renders superior stability of the interface between the electrolyte and the anode (e.g., smoothly running for over 580 h at 2 mA cm-2). No-corrosion and no-pulverization problems appear in this novel liquid/liquid interface. Those advantages demonstrate that the liquid Ga-metal anode has a great promise for the improvement of the NaCl-AlCl3-based Al-ion batteries for large-scale stationary energy storage applications.
KW - NaCl-AlCl-based Al-ion batteries
KW - liquid Ga metal
KW - long cycle life
KW - stable liquid/liquid interface
KW - stationary energy storage battery
UR - http://www.scopus.com/inward/record.url?scp=85082780390&partnerID=8YFLogxK
U2 - 10.1021/acsami.9b21809
DO - 10.1021/acsami.9b21809
M3 - Article
C2 - 32159940
AN - SCOPUS:85082780390
SN - 1944-8244
VL - 12
SP - 15063
EP - 15070
JO - ACS applied materials & interfaces
JF - ACS applied materials & interfaces
IS - 13
ER -