Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating

Qian Cheng; Aijun Li; Na Li; Shuang Li; Amirali Zangiabadi; Tai De Li; Wenlong Huang; Alex Ceng Li; Tianwei Jin; Qingquan Song; Weiheng Xu; Nan Ni; Haowei Zhai; Martin Dontigny; Karim Zaghib; Xiuyun Chuan; Dong Su; Kai Yan; Yuan Yang

doi:10.1016/j.joule.2019.03.022

Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating

Qian Cheng, Aijun Li, Na Li, Shuang Li, Amirali Zangiabadi, Tai De Li, Wenlong Huang, Alex Ceng Li, Tianwei Jin, Qingquan Song, Weiheng Xu, Nan Ni, Haowei Zhai, Martin Dontigny, Karim Zaghib, Xiuyun Chuan, Dong Su, Kai Yan^*, Yuan Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

257 Citations (Scopus)

Abstract

Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li_1.3Al_0.3Ti_1.7(PO₄)₃ (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with ∼1–2 μm PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA·cm⁻². In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO₄/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.

Original language	English
Pages (from-to)	1510-1522
Number of pages	13
Journal	Joule
Volume	3
Issue number	6
DOIs	https://doi.org/10.1016/j.joule.2019.03.022
Publication status	Published - 19 Jun 2019
Externally published	Yes

Keywords

boron nitride coating
chemical vapor deposition
in situ TEM
robust solid electrolyte/Li interface
solid electrolyte

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10.1016/j.joule.2019.03.022

Cite this

Cheng, Q., Li, A., Li, N., Li, S., Zangiabadi, A., Li, T. D., Huang, W., Li, A. C., Jin, T., Song, Q., Xu, W., Ni, N., Zhai, H., Dontigny, M., Zaghib, K., Chuan, X., Su, D., Yan, K., & Yang, Y. (2019). Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating. Joule, 3(6), 1510-1522. https://doi.org/10.1016/j.joule.2019.03.022

@article{ed69ddf5627c4f5c943526031de0843d,

title = "Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating",

abstract = "Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with ∼1–2 μm PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA·cm−2. In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO4/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.",

keywords = "boron nitride coating, chemical vapor deposition, in situ TEM, robust solid electrolyte/Li interface, solid electrolyte",

author = "Qian Cheng and Aijun Li and Na Li and Shuang Li and Amirali Zangiabadi and Li, {Tai De} and Wenlong Huang and Li, {Alex Ceng} and Tianwei Jin and Qingquan Song and Weiheng Xu and Nan Ni and Haowei Zhai and Martin Dontigny and Karim Zaghib and Xiuyun Chuan and Dong Su and Kai Yan and Yuan Yang",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Inc.",

year = "2019",

month = jun,

day = "19",

doi = "10.1016/j.joule.2019.03.022",

language = "English",

volume = "3",

pages = "1510--1522",

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Cheng, Q, Li, A, Li, N, Li, S, Zangiabadi, A, Li, TD, Huang, W, Li, AC, Jin, T, Song, Q, Xu, W, Ni, N, Zhai, H, Dontigny, M, Zaghib, K, Chuan, X, Su, D, Yan, K & Yang, Y 2019, 'Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating', Joule, vol. 3, no. 6, pp. 1510-1522. https://doi.org/10.1016/j.joule.2019.03.022

TY - JOUR

T1 - Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating

AU - Cheng, Qian

AU - Li, Aijun

AU - Li, Na

AU - Li, Shuang

AU - Zangiabadi, Amirali

AU - Li, Tai De

AU - Huang, Wenlong

AU - Li, Alex Ceng

AU - Jin, Tianwei

AU - Song, Qingquan

AU - Xu, Weiheng

AU - Ni, Nan

AU - Zhai, Haowei

AU - Dontigny, Martin

AU - Zaghib, Karim

AU - Chuan, Xiuyun

AU - Su, Dong

AU - Yan, Kai

AU - Yang, Yuan

PY - 2019/6/19

Y1 - 2019/6/19

N2 - Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with ∼1–2 μm PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA·cm−2. In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO4/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.

AB - Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with ∼1–2 μm PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA·cm−2. In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO4/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.

KW - boron nitride coating

KW - chemical vapor deposition

KW - in situ TEM

KW - robust solid electrolyte/Li interface

KW - solid electrolyte

UR - http://www.scopus.com/inward/record.url?scp=85066993986&partnerID=8YFLogxK

U2 - 10.1016/j.joule.2019.03.022

DO - 10.1016/j.joule.2019.03.022

M3 - Article

AN - SCOPUS:85066993986

SN - 2542-4351

VL - 3

SP - 1510

EP - 1522

JO - Joule

JF - Joule

IS - 6

ER -

Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating

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Keywords

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