TY - JOUR
T1 - Stabilization and Emission Characteristics of Gliding Arc-Assisted NH3/CH4/Air Premixed Flames in a Swirl Combustor
AU - Sun, Jinguo
AU - Huang, Qian
AU - Tang, Yong
AU - Li, Shuiqing
N1 - Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.
PY - 2022/8/4
Y1 - 2022/8/4
N2 - This paper investigates the effects of gliding arc (GA) discharge on the stabilization and emission characteristics of premixed NH3/CH4/air swirl flames under various ammonia contents, flow rates, and global equivalence ratios. First, the lean blowout (LBO) limits are measured. We find that although blending CH4extends the LBO limit of the ammonia flame to 0.6-0.8, the GA discharge further remarkably extends it to 0.3-0.4. Then, the flow and flame structures are visualized by simultaneous OH planar laser-induced fluorescence and particle imaging velocimetry measurements. The results reveal that the discharge increases the OH radical concentration and expands the inner recirculation zone, leading to improved flame stability. Second, the NOxemissions are investigated over a wide range of global equivalence ratios and ammonia contents. It is seen that the GA discharge slightly increases the NOxemission by less than 7% at low NH3contents (<0.6), which can be attributed to the thermal and OH-involved reaction pathway of NOxformation. However, as the NH3content further increases (which is accompanied by the rapid growth of the NOxemission), the GA discharge effectively reduces the NOxemission by up to 30%. This effect might be due to the more intensive NOx-consuming reactions by plasma-induced NH2radicals at a higher ammonia content, which is confirmed by the strengthened NH2∗ chemiluminescence under GA discharge conditions. Finally, a chemical reactor network analysis gives reasonable NOxpredictions without GA discharge and highlights the NOx-reduction effects of NH2radicals under high ammonia contents.
AB - This paper investigates the effects of gliding arc (GA) discharge on the stabilization and emission characteristics of premixed NH3/CH4/air swirl flames under various ammonia contents, flow rates, and global equivalence ratios. First, the lean blowout (LBO) limits are measured. We find that although blending CH4extends the LBO limit of the ammonia flame to 0.6-0.8, the GA discharge further remarkably extends it to 0.3-0.4. Then, the flow and flame structures are visualized by simultaneous OH planar laser-induced fluorescence and particle imaging velocimetry measurements. The results reveal that the discharge increases the OH radical concentration and expands the inner recirculation zone, leading to improved flame stability. Second, the NOxemissions are investigated over a wide range of global equivalence ratios and ammonia contents. It is seen that the GA discharge slightly increases the NOxemission by less than 7% at low NH3contents (<0.6), which can be attributed to the thermal and OH-involved reaction pathway of NOxformation. However, as the NH3content further increases (which is accompanied by the rapid growth of the NOxemission), the GA discharge effectively reduces the NOxemission by up to 30%. This effect might be due to the more intensive NOx-consuming reactions by plasma-induced NH2radicals at a higher ammonia content, which is confirmed by the strengthened NH2∗ chemiluminescence under GA discharge conditions. Finally, a chemical reactor network analysis gives reasonable NOxpredictions without GA discharge and highlights the NOx-reduction effects of NH2radicals under high ammonia contents.
UR - http://www.scopus.com/inward/record.url?scp=85135590677&partnerID=8YFLogxK
U2 - 10.1021/acs.energyfuels.2c01217
DO - 10.1021/acs.energyfuels.2c01217
M3 - Article
AN - SCOPUS:85135590677
SN - 0887-0624
VL - 36
SP - 8520
EP - 8527
JO - Energy and Fuels
JF - Energy and Fuels
IS - 15
ER -