Solvothermal synthesis, structure and Mössbauer spectroscopy of a new mixed-valence iron aluminophosphate [FeII(H2O)2 Fe0.8IIIAl1.2 (PO4)3]·H3O

Li Peng; Jiyang Li; Jihong Yu; Guanghua Li; Qianrong Fang; Ruren Xu

doi:10.1016/j.crci.2004.10.027

Solvothermal synthesis, structure and Mössbauer spectroscopy of a new mixed-valence iron aluminophosphate [Fe^II(H₂O)₂ Fe_0.8^IIIAl_1.2 (PO₄)₃]·H₃O

Li Peng, Jiyang Li^*, Jihong Yu, Guanghua Li, Qianrong Fang, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A new mixed-valence open-framework iron aluminumphosphate [Fe^II(H₂O)₂Fe_0.8 ^IIIAl_1.2(PO₄)₃]· H₃O (I) has been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction, compositional analyses, TG-TDA and ⁵⁷Fe powder absorption M̈ssbauer spectroscopy. Compound I crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.3200(14) Å, b = 10.2104(11) Å, c = 8.8412(9) Å, β = 108.590(2), and Z = 4 with R₁ =0.0525 (I > 2 σ(I)). Its open-framework structure is built up from distorted Fe^IIO₄(H₂O)₂ octahedra, AlO₅/Fe^IIIO₅ trigonal dipyramids and PO₄ tetrahedra, which possesses 8-memebered ring (MR) channels along [001] direction.

Original language	English
Pages (from-to)	541-547
Number of pages	7
Journal	Comptes Rendus Chimie
Volume	8
Issue number	3-4
DOIs	https://doi.org/10.1016/j.crci.2004.10.027
Publication status	Published - Mar 2005
Externally published	Yes

Keywords

Iron aluminophosphate
Mixed-valence
Open-framework structure
Solvothermal synthesis

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10.1016/j.crci.2004.10.027

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@article{c1350afa415d4ecfbc571a6bb537b05e,

title = "Solvothermal synthesis, structure and M{\"o}ssbauer spectroscopy of a new mixed-valence iron aluminophosphate [FeII(H2O)2 Fe0.8IIIAl1.2 (PO4)3]·H3O",

abstract = "A new mixed-valence open-framework iron aluminumphosphate [FeII(H2O)2Fe0.8 IIIAl1.2(PO4)3]· H3O (I) has been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction, compositional analyses, TG-TDA and 57Fe powder absorption {\"M}ssbauer spectroscopy. Compound I crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.3200(14) {\AA}, b = 10.2104(11) {\AA}, c = 8.8412(9) {\AA}, β = 108.590(2), and Z = 4 with R1 =0.0525 (I > 2 σ(I)). Its open-framework structure is built up from distorted FeIIO4(H2O)2 octahedra, AlO5/FeIIIO5 trigonal dipyramids and PO4 tetrahedra, which possesses 8-memebered ring (MR) channels along [001] direction.",

keywords = "Iron aluminophosphate, Mixed-valence, Open-framework structure, Solvothermal synthesis",

author = "Li Peng and Jiyang Li and Jihong Yu and Guanghua Li and Qianrong Fang and Ruren Xu",

year = "2005",

month = mar,

doi = "10.1016/j.crci.2004.10.027",

language = "English",

volume = "8",

pages = "541--547",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

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T1 - Solvothermal synthesis, structure and Mössbauer spectroscopy of a new mixed-valence iron aluminophosphate [FeII(H2O)2 Fe0.8IIIAl1.2 (PO4)3]·H3O

AU - Peng, Li

AU - Li, Jiyang

AU - Yu, Jihong

AU - Li, Guanghua

AU - Fang, Qianrong

AU - Xu, Ruren

PY - 2005/3

Y1 - 2005/3

N2 - A new mixed-valence open-framework iron aluminumphosphate [FeII(H2O)2Fe0.8 IIIAl1.2(PO4)3]· H3O (I) has been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction, compositional analyses, TG-TDA and 57Fe powder absorption M̈ssbauer spectroscopy. Compound I crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.3200(14) Å, b = 10.2104(11) Å, c = 8.8412(9) Å, β = 108.590(2), and Z = 4 with R1 =0.0525 (I > 2 σ(I)). Its open-framework structure is built up from distorted FeIIO4(H2O)2 octahedra, AlO5/FeIIIO5 trigonal dipyramids and PO4 tetrahedra, which possesses 8-memebered ring (MR) channels along [001] direction.

AB - A new mixed-valence open-framework iron aluminumphosphate [FeII(H2O)2Fe0.8 IIIAl1.2(PO4)3]· H3O (I) has been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction, compositional analyses, TG-TDA and 57Fe powder absorption M̈ssbauer spectroscopy. Compound I crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.3200(14) Å, b = 10.2104(11) Å, c = 8.8412(9) Å, β = 108.590(2), and Z = 4 with R1 =0.0525 (I > 2 σ(I)). Its open-framework structure is built up from distorted FeIIO4(H2O)2 octahedra, AlO5/FeIIIO5 trigonal dipyramids and PO4 tetrahedra, which possesses 8-memebered ring (MR) channels along [001] direction.

KW - Iron aluminophosphate

KW - Mixed-valence

KW - Open-framework structure

KW - Solvothermal synthesis

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DO - 10.1016/j.crci.2004.10.027

M3 - Article

AN - SCOPUS:17544380656

SN - 1631-0748

VL - 8

SP - 541

EP - 547

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

IS - 3-4

ER -

Solvothermal synthesis, structure and Mössbauer spectroscopy of a new mixed-valence iron aluminophosphate [Fe^II(H₂O)₂ Fe_0.8^IIIAl_1.2 (PO₄)₃]·H₃O

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