Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions

J. Yu; O. Terasaki; I. D. Williams; S. Quiv; R. Xu

doi:10.1016/S0968-5677(98)00022-4

Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions

J. Yu^*, O. Terasaki, I. D. Williams, S. Quiv, R. Xu

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

20 Citations (Scopus)

Abstract

Two imidazolium templated aluminophosphate layers, [N₂C₃H₅]₂ [Al₃P₄O₁₆H] (1) and [N₂C₃H₅] [AlP₂O₈H₂(OH₂)₂] (2), have been synthesized under solvothermal conditions at 160°C. The effects of P/Al ratio, the amount of organic amine and the type of solvent on the products are investigated. Their structures are characterized by single-crystal X-ray diffraction (XRD), powder XRD, ²⁷Al DOR NMR, ³¹P MAS NMR and thermal analyses. Both compounds exhibit unusual structure architectures which are different from previously reported [Al₃P₄O₁₆]^3- and [AlP₂O₈]^3- families. Compound 1 crystallizes in the triclinic space group of P1̄ (No. 2) with a = 8.940(2), b = 9.360(2), c = 11.721(2)A, α = 97.10(2), β = 95.10(2), γ = 91.91(2)°, V = 968.4(3)A³ and Z = 2. The structure contains a new macroanionic inorganic sheet characterized by a series of double six-membered ring (D6R), in which Al moieties (including AlO₄ and AlO₅) and P moieties [including PO₄, PO₃(= O) and PO₂(= O) (OH)] are corner-shared through oxygen in an alternative manner. Compound 2 crystallizes in the monoclinic space group of C2/c (No. 15) with a = 21.854(4), b = 7.188(2), c = 6.990(2)A, β = 103.77(2)°, V = 1063.5(5)A³ and Z = 4. The structure is based on a new two-dimensionally connected inorganic network containing eight-membered rings in which AlO₄(OH₂)₂ and PO₂(OH) (= O) units are connected alternatively.

Original language	English
Pages (from-to)	297-302
Number of pages	6
Journal	Supramolecular Science
Volume	5
Issue number	3-4
DOIs	https://doi.org/10.1016/S0968-5677(98)00022-4
Publication status	Published - 1 Sept 1998
Externally published	Yes
Event	Proceedings of the 11th Toyota Conference on Nanostructured Materials in Biological and Artificial Systems - Shizuoka, Jpn Duration: 5 Nov 1997 → 8 Nov 1997

Access to Document

10.1016/S0968-5677(98)00022-4

Cite this

@article{c0e48c7e44ca4055acaaf9a27b5ee96a,

title = "Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions",

abstract = "Two imidazolium templated aluminophosphate layers, [N2C3H5]2 [Al3P4O16H] (1) and [N2C3H5] [AlP2O8H2(OH2)2] (2), have been synthesized under solvothermal conditions at 160°C. The effects of P/Al ratio, the amount of organic amine and the type of solvent on the products are investigated. Their structures are characterized by single-crystal X-ray diffraction (XRD), powder XRD, 27Al DOR NMR, 31P MAS NMR and thermal analyses. Both compounds exhibit unusual structure architectures which are different from previously reported [Al3P4O16]3- and [AlP2O8]3- families. Compound 1 crystallizes in the triclinic space group of P{\=1} (No. 2) with a = 8.940(2), b = 9.360(2), c = 11.721(2)A, α = 97.10(2), β = 95.10(2), γ = 91.91(2)°, V = 968.4(3)A3 and Z = 2. The structure contains a new macroanionic inorganic sheet characterized by a series of double six-membered ring (D6R), in which Al moieties (including AlO4 and AlO5) and P moieties [including PO4, PO3(= O) and PO2(= O) (OH)] are corner-shared through oxygen in an alternative manner. Compound 2 crystallizes in the monoclinic space group of C2/c (No. 15) with a = 21.854(4), b = 7.188(2), c = 6.990(2)A, β = 103.77(2)°, V = 1063.5(5)A3 and Z = 4. The structure is based on a new two-dimensionally connected inorganic network containing eight-membered rings in which AlO4(OH2)2 and PO2(OH) (= O) units are connected alternatively.",

author = "J. Yu and O. Terasaki and Williams, {I. D.} and S. Quiv and R. Xu",

year = "1998",

month = sep,

day = "1",

doi = "10.1016/S0968-5677(98)00022-4",

language = "English",

volume = "5",

pages = "297--302",

journal = "Supramolecular Science",

issn = "0968-5677",

publisher = "Elsevier B.V.",

number = "3-4",

note = "Proceedings of the 11th Toyota Conference on Nanostructured Materials in Biological and Artificial Systems ; Conference date: 05-11-1997 Through 08-11-1997",

}

TY - JOUR

T1 - Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions

AU - Yu, J.

AU - Terasaki, O.

AU - Williams, I. D.

AU - Quiv, S.

AU - Xu, R.

PY - 1998/9/1

Y1 - 1998/9/1

N2 - Two imidazolium templated aluminophosphate layers, [N2C3H5]2 [Al3P4O16H] (1) and [N2C3H5] [AlP2O8H2(OH2)2] (2), have been synthesized under solvothermal conditions at 160°C. The effects of P/Al ratio, the amount of organic amine and the type of solvent on the products are investigated. Their structures are characterized by single-crystal X-ray diffraction (XRD), powder XRD, 27Al DOR NMR, 31P MAS NMR and thermal analyses. Both compounds exhibit unusual structure architectures which are different from previously reported [Al3P4O16]3- and [AlP2O8]3- families. Compound 1 crystallizes in the triclinic space group of P1̄ (No. 2) with a = 8.940(2), b = 9.360(2), c = 11.721(2)A, α = 97.10(2), β = 95.10(2), γ = 91.91(2)°, V = 968.4(3)A3 and Z = 2. The structure contains a new macroanionic inorganic sheet characterized by a series of double six-membered ring (D6R), in which Al moieties (including AlO4 and AlO5) and P moieties [including PO4, PO3(= O) and PO2(= O) (OH)] are corner-shared through oxygen in an alternative manner. Compound 2 crystallizes in the monoclinic space group of C2/c (No. 15) with a = 21.854(4), b = 7.188(2), c = 6.990(2)A, β = 103.77(2)°, V = 1063.5(5)A3 and Z = 4. The structure is based on a new two-dimensionally connected inorganic network containing eight-membered rings in which AlO4(OH2)2 and PO2(OH) (= O) units are connected alternatively.

AB - Two imidazolium templated aluminophosphate layers, [N2C3H5]2 [Al3P4O16H] (1) and [N2C3H5] [AlP2O8H2(OH2)2] (2), have been synthesized under solvothermal conditions at 160°C. The effects of P/Al ratio, the amount of organic amine and the type of solvent on the products are investigated. Their structures are characterized by single-crystal X-ray diffraction (XRD), powder XRD, 27Al DOR NMR, 31P MAS NMR and thermal analyses. Both compounds exhibit unusual structure architectures which are different from previously reported [Al3P4O16]3- and [AlP2O8]3- families. Compound 1 crystallizes in the triclinic space group of P1̄ (No. 2) with a = 8.940(2), b = 9.360(2), c = 11.721(2)A, α = 97.10(2), β = 95.10(2), γ = 91.91(2)°, V = 968.4(3)A3 and Z = 2. The structure contains a new macroanionic inorganic sheet characterized by a series of double six-membered ring (D6R), in which Al moieties (including AlO4 and AlO5) and P moieties [including PO4, PO3(= O) and PO2(= O) (OH)] are corner-shared through oxygen in an alternative manner. Compound 2 crystallizes in the monoclinic space group of C2/c (No. 15) with a = 21.854(4), b = 7.188(2), c = 6.990(2)A, β = 103.77(2)°, V = 1063.5(5)A3 and Z = 4. The structure is based on a new two-dimensionally connected inorganic network containing eight-membered rings in which AlO4(OH2)2 and PO2(OH) (= O) units are connected alternatively.

UR - http://www.scopus.com/inward/record.url?scp=0032108533&partnerID=8YFLogxK

U2 - 10.1016/S0968-5677(98)00022-4

DO - 10.1016/S0968-5677(98)00022-4

M3 - Conference article

AN - SCOPUS:0032108533

SN - 0968-5677

VL - 5

SP - 297

EP - 302

JO - Supramolecular Science

JF - Supramolecular Science

IS - 3-4

T2 - Proceedings of the 11th Toyota Conference on Nanostructured Materials in Biological and Artificial Systems

Y2 - 5 November 1997 through 8 November 1997

ER -

Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this