Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

Chun Ding Zhou; Chao Chen; Li Xuan Cai; Jie Zhang

doi:10.1039/c2dt12260j

Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

Chun Ding Zhou, Chao Chen, Li Xuan Cai, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A one-dimensional iron(ii) coordination polymer, [Fe ₃(hpdc) ₂(H ₂O) ₆]·2H ₂O (H ₃hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

Original language	English
Pages (from-to)	5912-5918
Number of pages	7
Journal	Dalton Transactions
Volume	41
Issue number	19
DOIs	https://doi.org/10.1039/c2dt12260j
Publication status	Published - 21 May 2012
Externally published	Yes

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title = "Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition",

abstract = "A one-dimensional iron(ii) coordination polymer, [Fe 3(hpdc) 2(H 2O) 6]·2H 2O (H 3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.",

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T1 - Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

AU - Zhou, Chun Ding

AU - Chen, Chao

AU - Cai, Li Xuan

AU - Zhang, Jie

PY - 2012/5/21

Y1 - 2012/5/21

N2 - A one-dimensional iron(ii) coordination polymer, [Fe 3(hpdc) 2(H 2O) 6]·2H 2O (H 3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

AB - A one-dimensional iron(ii) coordination polymer, [Fe 3(hpdc) 2(H 2O) 6]·2H 2O (H 3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

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U2 - 10.1039/c2dt12260j

DO - 10.1039/c2dt12260j

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VL - 41

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EP - 5918

JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

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