TY - JOUR
T1 - Solid-state [2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4′-pyridyl)ethylene
AU - Jia, Mengze
AU - Sun, Li
AU - Chen, Yunrui
AU - Zhang, Jie
N1 - Publisher Copyright:
© 2021, Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH.
PY - 2022/2
Y1 - 2022/2
N2 - A photoactive metal-organic complex [Zn2(BCbpe)2(p-DBC)2]·5H2O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl] pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.
AB - A photoactive metal-organic complex [Zn2(BCbpe)2(p-DBC)2]·5H2O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl] pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.
KW - Pyridinium
KW - Solid-state photoreaction
KW - [2+2] cycloaddition
UR - http://www.scopus.com/inward/record.url?scp=85111100001&partnerID=8YFLogxK
U2 - 10.1007/s40242-021-1226-z
DO - 10.1007/s40242-021-1226-z
M3 - Article
AN - SCOPUS:85111100001
SN - 1005-9040
VL - 38
SP - 181
EP - 185
JO - Chemical Research in Chinese Universities
JF - Chemical Research in Chinese Universities
IS - 1
ER -