Size Dependence of Charge-Density-Wave Orders in Single-Layer NbSe2 Hetero/Homophase Junctions

Zeping Huang, Xuan Song, Yaoyao Chen, Han Yang, Peiwen Yuan, Hang Ma, Jingsi Qiao, Yu Zhang, Jiatao Sun, Teng Zhang, Yuan Huang, Liwei Liu*, Hong Jun Gao, Yeliang Wang*

*Corresponding author for this work

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Abstract

Controlling charge-density-wave (CDW) orders in two-dimensional (2D) crystals has attracted a great deal of interest because of their fundamental physics and their demand inse in miniaturized devices. In this work, we systematically studied the size-dependent CDW orders in single-layer hetero/homo-NbSe2 stacking junctions. We found that the CDW orders in the top 1T-NbSe2 layer of the junctions are highly dependent on its lateral size. For the 1T/2H-NbSe2 heterojunction, the critical lateral size of 1T-NbSe2 islands for the formation of well-defined CDW orders is ∼26 nm, whereas below 15 nm, the CDW orders melt. However, for the 1T/1T-NbSe2 homojunction, the CDW orders in the islands can persist even with a lateral size of <11 nm. Our findings illuminate the fresh phenomenon of size-dependent CDW orders existing in 2D van der Waals hetero/homojunctions and provide useful information for the control of CDW orders.

Original languageEnglish
Pages (from-to)1901-1907
Number of pages7
JournalJournal of Physical Chemistry Letters
Volume13
Issue number8
DOIs
Publication statusPublished - 3 Mar 2022

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Huang, Z., Song, X., Chen, Y., Yang, H., Yuan, P., Ma, H., Qiao, J., Zhang, Y., Sun, J., Zhang, T., Huang, Y., Liu, L., Gao, H. J., & Wang, Y. (2022). Size Dependence of Charge-Density-Wave Orders in Single-Layer NbSe2 Hetero/Homophase Junctions. Journal of Physical Chemistry Letters, 13(8), 1901-1907. https://doi.org/10.1021/acs.jpclett.1c04138