Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

Jing Jiang; Yong Zhang; Hu Wei Liu; Ai Qin Luo; Yu Lin Deng; Jun Ling Gu

Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

Jing Jiang^*, Yong Zhang, Hu Wei Liu, Ai Qin Luo, Yu Lin Deng, Jun Ling Gu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 10⁷ plates/m and high resolution. The method was demonstrated to be efficient by comparing with C₁₈-packed column CEC method and high performance liquid chromatography (HPLC) method.

Original language	English
Pages (from-to)	372-376
Number of pages	5
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	25
Issue number	4
Publication status	Published - Apr 2005

Keywords

DB-β-CD
Open-tubular capillary electrochromatography column
Sol-gel

Cite this

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title = "Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives",

abstract = "The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 107 plates/m and high resolution. The method was demonstrated to be efficient by comparing with C18-packed column CEC method and high performance liquid chromatography (HPLC) method.",

keywords = "DB-β-CD, Open-tubular capillary electrochromatography column, Sol-gel",

author = "Jing Jiang and Yong Zhang and Liu, {Hu Wei} and Luo, {Ai Qin} and Deng, {Yu Lin} and Gu, {Jun Ling}",

year = "2005",

month = apr,

language = "English",

volume = "25",

pages = "372--376",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

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TY - JOUR

T1 - Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

AU - Jiang, Jing

AU - Zhang, Yong

AU - Liu, Hu Wei

AU - Luo, Ai Qin

AU - Deng, Yu Lin

AU - Gu, Jun Ling

PY - 2005/4

Y1 - 2005/4

N2 - The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 107 plates/m and high resolution. The method was demonstrated to be efficient by comparing with C18-packed column CEC method and high performance liquid chromatography (HPLC) method.

AB - The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 107 plates/m and high resolution. The method was demonstrated to be efficient by comparing with C18-packed column CEC method and high performance liquid chromatography (HPLC) method.

KW - DB-β-CD

KW - Open-tubular capillary electrochromatography column

KW - Sol-gel

UR - http://www.scopus.com/inward/record.url?scp=20444412660&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:20444412660

SN - 1001-0645

VL - 25

SP - 372

EP - 376

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 4

ER -

Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

Abstract

Keywords

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