Selective hydrogenation of SBS catalyzed by Ru/TPPTS complex in polyether modified ammonium salt ionic liquid

Li Wei; Jingyang Jiang; Yanhua Wang; Zilin Jin

doi:10.1016/j.molcata.2004.07.005

Selective hydrogenation of SBS catalyzed by Ru/TPPTS complex in polyether modified ammonium salt ionic liquid

Li Wei, Jingyang Jiang^*, Yanhua Wang, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

The hydrogenation of SBS catalyzed by Ru/TPPTS complex was performed in polyether modified ammonium salt ionic liquid biphasic system. It has been observed that the hydrogenation degree can be increased by addition of "promoter ligand" TPP. Under the optimized conditions of T = 150 °C, t = 12 h, P = 5.0 MPa, Ru/TPPTS/TPP = 1:5:2, the hydrogenation degree of the polybutadiene segments of SBS was 89%. In addition, no hydrogenation takes place on the benzene ring. The Ru catalyst immobilized in ionic liquid can be recovered simply by phase separation and recycled three times without significant changes in the catalytic activity.

Original language	English
Pages (from-to)	47-50
Number of pages	4
Journal	Journal of Molecular Catalysis A: Chemical
Volume	221
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2004.07.005
Publication status	Published - 1 Nov 2004
Externally published	Yes

Keywords

Hydrogenation
Polyether modified ammonium salt ionic liquid
Ruthenium complex
SBS

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10.1016/j.molcata.2004.07.005

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title = "Selective hydrogenation of SBS catalyzed by Ru/TPPTS complex in polyether modified ammonium salt ionic liquid",

abstract = "The hydrogenation of SBS catalyzed by Ru/TPPTS complex was performed in polyether modified ammonium salt ionic liquid biphasic system. It has been observed that the hydrogenation degree can be increased by addition of {"}promoter ligand{"} TPP. Under the optimized conditions of T = 150 °C, t = 12 h, P = 5.0 MPa, Ru/TPPTS/TPP = 1:5:2, the hydrogenation degree of the polybutadiene segments of SBS was 89%. In addition, no hydrogenation takes place on the benzene ring. The Ru catalyst immobilized in ionic liquid can be recovered simply by phase separation and recycled three times without significant changes in the catalytic activity.",

keywords = "Hydrogenation, Polyether modified ammonium salt ionic liquid, Ruthenium complex, SBS",

author = "Li Wei and Jingyang Jiang and Yanhua Wang and Zilin Jin",

year = "2004",

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doi = "10.1016/j.molcata.2004.07.005",

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T1 - Selective hydrogenation of SBS catalyzed by Ru/TPPTS complex in polyether modified ammonium salt ionic liquid

AU - Wei, Li

AU - Jiang, Jingyang

AU - Wang, Yanhua

AU - Jin, Zilin

PY - 2004/11/1

Y1 - 2004/11/1

N2 - The hydrogenation of SBS catalyzed by Ru/TPPTS complex was performed in polyether modified ammonium salt ionic liquid biphasic system. It has been observed that the hydrogenation degree can be increased by addition of "promoter ligand" TPP. Under the optimized conditions of T = 150 °C, t = 12 h, P = 5.0 MPa, Ru/TPPTS/TPP = 1:5:2, the hydrogenation degree of the polybutadiene segments of SBS was 89%. In addition, no hydrogenation takes place on the benzene ring. The Ru catalyst immobilized in ionic liquid can be recovered simply by phase separation and recycled three times without significant changes in the catalytic activity.

AB - The hydrogenation of SBS catalyzed by Ru/TPPTS complex was performed in polyether modified ammonium salt ionic liquid biphasic system. It has been observed that the hydrogenation degree can be increased by addition of "promoter ligand" TPP. Under the optimized conditions of T = 150 °C, t = 12 h, P = 5.0 MPa, Ru/TPPTS/TPP = 1:5:2, the hydrogenation degree of the polybutadiene segments of SBS was 89%. In addition, no hydrogenation takes place on the benzene ring. The Ru catalyst immobilized in ionic liquid can be recovered simply by phase separation and recycled three times without significant changes in the catalytic activity.

KW - Hydrogenation

KW - Polyether modified ammonium salt ionic liquid

KW - Ruthenium complex

KW - SBS

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U2 - 10.1016/j.molcata.2004.07.005

DO - 10.1016/j.molcata.2004.07.005

M3 - Article

AN - SCOPUS:4544241409

SN - 1381-1169

VL - 221

SP - 47

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JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Selective hydrogenation of SBS catalyzed by Ru/TPPTS complex in polyether modified ammonium salt ionic liquid

Abstract

Keywords

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