Ru@UiO-66(Ce) catalyzed acceptorless dehydrogenation of primary amines to nitriles: The roles of Lewis acid-base pairs in the reaction

Guo Ping Lu; Xinxin Li; Lixiang Zhong; Shuzhou Li; Fei Chen

doi:10.1039/c9gc02181g

Ru@UiO-66(Ce) catalyzed acceptorless dehydrogenation of primary amines to nitriles: The roles of Lewis acid-base pairs in the reaction

Guo Ping Lu^*, Xinxin Li, Lixiang Zhong, Shuzhou Li, Fei Chen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

UiO-66(Ce)-encapsulated ruthenium nanoparticles (Ru@UiO-66(Ce)) was designed and used for dehydrogenation of primary amines to nitriles in water without any hydrogen acceptors and additives. Introduction of metal Ru to UiO-66(Ce) contributes to the formation of Lewis acid-base pairs on the catalyst owing to the metal-support interaction, acting as active sites for activation of amines and transfer of hydrogen. Ab initio calculation results further confirm the roles of Lewis acid-base pairs in the reaction.

Original language	English
Pages (from-to)	5386-5393
Number of pages	8
Journal	Green Chemistry
Volume	21
Issue number	19
DOIs	https://doi.org/10.1039/c9gc02181g
Publication status	Published - 2019
Externally published	Yes

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title = "Ru@UiO-66(Ce) catalyzed acceptorless dehydrogenation of primary amines to nitriles: The roles of Lewis acid-base pairs in the reaction",

abstract = "UiO-66(Ce)-encapsulated ruthenium nanoparticles (Ru@UiO-66(Ce)) was designed and used for dehydrogenation of primary amines to nitriles in water without any hydrogen acceptors and additives. Introduction of metal Ru to UiO-66(Ce) contributes to the formation of Lewis acid-base pairs on the catalyst owing to the metal-support interaction, acting as active sites for activation of amines and transfer of hydrogen. Ab initio calculation results further confirm the roles of Lewis acid-base pairs in the reaction.",

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doi = "10.1039/c9gc02181g",

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T1 - Ru@UiO-66(Ce) catalyzed acceptorless dehydrogenation of primary amines to nitriles

T2 - The roles of Lewis acid-base pairs in the reaction

AU - Lu, Guo Ping

AU - Li, Xinxin

AU - Zhong, Lixiang

AU - Li, Shuzhou

AU - Chen, Fei

PY - 2019

Y1 - 2019

N2 - UiO-66(Ce)-encapsulated ruthenium nanoparticles (Ru@UiO-66(Ce)) was designed and used for dehydrogenation of primary amines to nitriles in water without any hydrogen acceptors and additives. Introduction of metal Ru to UiO-66(Ce) contributes to the formation of Lewis acid-base pairs on the catalyst owing to the metal-support interaction, acting as active sites for activation of amines and transfer of hydrogen. Ab initio calculation results further confirm the roles of Lewis acid-base pairs in the reaction.

AB - UiO-66(Ce)-encapsulated ruthenium nanoparticles (Ru@UiO-66(Ce)) was designed and used for dehydrogenation of primary amines to nitriles in water without any hydrogen acceptors and additives. Introduction of metal Ru to UiO-66(Ce) contributes to the formation of Lewis acid-base pairs on the catalyst owing to the metal-support interaction, acting as active sites for activation of amines and transfer of hydrogen. Ab initio calculation results further confirm the roles of Lewis acid-base pairs in the reaction.

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U2 - 10.1039/c9gc02181g

DO - 10.1039/c9gc02181g

M3 - Article

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SN - 1463-9262

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JO - Green Chemistry

JF - Green Chemistry

IS - 19

ER -

Ru@UiO-66(Ce) catalyzed acceptorless dehydrogenation of primary amines to nitriles: The roles of Lewis acid-base pairs in the reaction

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