Russian-doll-type metal carbide endofullerene: Synthesis, isolation, and characterization of Sc4C2@C80

Tai Shan Wang; Ning Chen; Jun Feng Xiang; Bao Li; Jing Yi Wu; Wei Xu; Li Jiang; Kai Tan; Chun Ying Shu; Xin Lu; Chun Ru Wang

doi:10.1021/ja9077842

Russian-doll-type metal carbide endofullerene: Synthesis, isolation, and characterization of Sc₄C₂@C₈₀

Tai Shan Wang, Ning Chen, Jun Feng Xiang, Bao Li, Jing Yi Wu, Wei Xu, Li Jiang, Kai Tan, Chun Ying Shu^*, Xin Lu, Chun Ru Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

117 Citations (Scopus)

Abstract

(Figure Presented) For the first time, we have produced the stable compound Sc₄C₂@C₈₀-I_h and characterized it as a metal carbide endofullerene by FTIR and Raman spectroscopies in combination with DFT calculations. Furthermore, DFT calculations have demonstrated that this molecule has a Russian-doll-type structure, C₂@Sc ₄@C₈₀.

Original language	English
Pages (from-to)	16646-16647
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	46
DOIs	https://doi.org/10.1021/ja9077842
Publication status	Published - 2009
Externally published	Yes

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title = "Russian-doll-type metal carbide endofullerene: Synthesis, isolation, and characterization of Sc4C2@C80",

abstract = "(Figure Presented) For the first time, we have produced the stable compound Sc4C2@C80-Ih and characterized it as a metal carbide endofullerene by FTIR and Raman spectroscopies in combination with DFT calculations. Furthermore, DFT calculations have demonstrated that this molecule has a Russian-doll-type structure, C2@Sc 4@C80.",

author = "Wang, {Tai Shan} and Ning Chen and Xiang, {Jun Feng} and Bao Li and Wu, {Jing Yi} and Wei Xu and Li Jiang and Kai Tan and Shu, {Chun Ying} and Xin Lu and Wang, {Chun Ru}",

year = "2009",

doi = "10.1021/ja9077842",

language = "English",

volume = "131",

pages = "16646--16647",

journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Russian-doll-type metal carbide endofullerene

T2 - Synthesis, isolation, and characterization of Sc4C2@C80

AU - Wang, Tai Shan

AU - Chen, Ning

AU - Xiang, Jun Feng

AU - Li, Bao

AU - Wu, Jing Yi

AU - Xu, Wei

AU - Jiang, Li

AU - Tan, Kai

AU - Shu, Chun Ying

AU - Lu, Xin

AU - Wang, Chun Ru

PY - 2009

Y1 - 2009

N2 - (Figure Presented) For the first time, we have produced the stable compound Sc4C2@C80-Ih and characterized it as a metal carbide endofullerene by FTIR and Raman spectroscopies in combination with DFT calculations. Furthermore, DFT calculations have demonstrated that this molecule has a Russian-doll-type structure, C2@Sc 4@C80.

AB - (Figure Presented) For the first time, we have produced the stable compound Sc4C2@C80-Ih and characterized it as a metal carbide endofullerene by FTIR and Raman spectroscopies in combination with DFT calculations. Furthermore, DFT calculations have demonstrated that this molecule has a Russian-doll-type structure, C2@Sc 4@C80.

UR - http://www.scopus.com/inward/record.url?scp=70450202396&partnerID=8YFLogxK

U2 - 10.1021/ja9077842

DO - 10.1021/ja9077842

M3 - Article

AN - SCOPUS:70450202396

SN - 0002-7863

VL - 131

SP - 16646

EP - 16647

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 46

ER -

Russian-doll-type metal carbide endofullerene: Synthesis, isolation, and characterization of Sc₄C₂@C₈₀

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